CaltechAUTHORS
  A Caltech Library Service

Discovery and Characterization of a Pourbaix-Stable, 1.8 eV Direct Gap Bismuth Manganate Photoanode

Newhouse, Paul F. and Reyes-Lillo, Sebastian E. and Li, Guo and Zhou, Lan and Shinde, Aniketa and Guevarra, Dan and Suram, Santosh K. and Soedarmadji, Edwin and Richter, Matthias H. and Qu, Xiaohui and Persson, Kristin and Neaton, Jeffrey B. and Gregoire, John M. (2017) Discovery and Characterization of a Pourbaix-Stable, 1.8 eV Direct Gap Bismuth Manganate Photoanode. Chemistry of Materials, 29 (23). pp. 10027-10036. ISSN 0897-4756. https://resolver.caltech.edu/CaltechAUTHORS:20171115-095753143

[img] PDF - Accepted Version
See Usage Policy.

2038Kb
[img] PDF (Eight figures and four tables with raw photoelectrochemical data, combinatorial measurements on PVD library, additional Pourbaix diagrams, electronic structure and cell parameters for four computed magnetic configurations, and slab calculation details) - Supplemental Material
See Usage Policy.

2886Kb

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20171115-095753143

Abstract

Solar-driven oxygen evolution is a critical technology for renewably synthesizing hydrogen- and carbon-containing fuels in solar fuel generators. New photoanode materials are needed to meet efficiency and stability requirements, motivating materials explorations for semiconductors with (i) band-gap energy in the visible spectrum and (ii) stable operation in aqueous electrolyte at the electrochemical potential needed to evolve oxygen from water. Motivated by the oxygen evolution competency of many Mn-based oxides, the existence of several Bi-containing ternary oxide photoanode materials, and the variety of known oxide materials combining these elements with Sm, we explore the Bi–Mn–Sm oxide system for new photoanodes. Through the use of a ferri/ferrocyanide redox couple in high-throughput screening, BiMn_2O_5 and its alloy with Sm are identified as photoanode materials with a near-ideal optical band gap of 1.8 eV. Using density functional theory-based calculations of the mullite Bi^(3+)Mn^(3+)Mn^(4+)O_5 phase, we identify electronic analogues to the well-known BiVO4 photoanode and demonstrate excellent Pourbaix stability above the oxygen evolution Nernstian potential from pH 4.5 to 15. Our suite of experimental and computational characterization indicates that BiMn_2O_5 is a complex oxide with the necessary optical and chemical properties to be an efficient, stable solar fuel photoanode.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/acs.chemmater.7b03591DOIArticle
http://pubs.acs.org/doi/10.1021/acs.chemmater.7b03591PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/acs.chemmater.7b03591PublisherSupporting Information
ORCID:
AuthorORCID
Zhou, Lan0000-0002-7052-266X
Shinde, Aniketa0000-0003-2386-3848
Guevarra, Dan0000-0002-9592-3195
Suram, Santosh K.0000-0001-8170-2685
Richter, Matthias H.0000-0003-0091-2045
Persson, Kristin0000-0003-2495-5509
Neaton, Jeffrey B.0000-0001-7585-6135
Gregoire, John M.0000-0002-2863-5265
Additional Information:© 2017 American Chemical Society. Received: August 25, 2017; Revised: November 13, 2017; Published: November 13, 2017. This material is based upon work performed by the Joint Center for Artificial Photosynthesis, a DOE Energy Innovation Hub, supported through the Office of Science of the U.S. Department of Energy (Award DE-SC0004993). Use of the Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Contract DE-AC02-76SF00515. Pourbaix diagram computation was supported by the Materials Project (BES DOE Grant EDCBEE). Work at the Molecular Foundry was supported by the Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract DE-AC02-05CH11231. We thank Apurva Mehta, Fang Ren, Douglas G. Van Campen, Tim Dunn, and Ryan Jones for assistance with collection of synchrotron XRD data. The authors declare no competing financial interest.
Group:JCAP
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-SC0004993
Department of Energy (DOE)DE-AC02-76SF00515
Department of Energy (DOE)DE-AC02-05CH11231
Issue or Number:23
Record Number:CaltechAUTHORS:20171115-095753143
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20171115-095753143
Official Citation:Discovery and Characterization of a Pourbaix-Stable, 1.8 eV Direct Gap Bismuth Manganate Photoanode. Paul F. Newhouse, Sebastian E. Reyes-Lillo, Guo Li, Lan Zhou, Aniketa Shinde, Dan Guevarra, Santosh K. Suram, Edwin Soedarmadji, Matthias H. Richter, Xiaohui Qu, Kristin Persson, Jeffrey B. Neaton, and John M. Gregoire. Chemistry of Materials 2017 29 (23), 10027-10036. DOI: 10.1021/acs.chemmater.7b03591
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:83218
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:15 Nov 2017 22:38
Last Modified:08 Oct 2019 22:25

Repository Staff Only: item control page