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Phase Boundary Mapping to Obtain n-type Mg_3Sb_2-Based Thermoelectrics

Ohno, Saneyuki and Imasato, Kazuki and Anand, Shashwat and Tamaki, Hiromasa and Kang, Stephen Dongmin and Gorai, Prashun and Sato, Hiroki K. and Toberer, Eric S. and Kanno, Tsutomu and Snyder, G. Jeffrey (2018) Phase Boundary Mapping to Obtain n-type Mg_3Sb_2-Based Thermoelectrics. Joule, 2 (1). pp. 141-154. ISSN 2542-4351. https://resolver.caltech.edu/CaltechAUTHORS:20171206-111345471

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Abstract

Zintl compounds make excellent thermoelectrics with many opportunities for chemically tuning their electronic and thermal transport properties. However, the majority of Zintl compounds are persistently p-type even though computation predicts superior properties when n-type. Surprisingly, n-type Mg_3Sb_2-based thermoelectrics have been recently found with exceptionally high figure of merit. Excess Mg is required to make the material n-type, prompting the suspicion that interstitial Mg is responsible. Here we explore the defect chemistry of Mg_3Sb_2 both theoretically and experimentally to explain why there are two distinct thermodynamic states for Mg_3Sb_2 (Mg-excess and Sb-excess) and why only one can become n-type. This work emphasizes the importance of exploring all of the multiple thermodynamic states in a nominally single-phase semiconductor. This understanding of the existence of multiple inherently distinct different thermodynamic states of the same nominal compound will vastly multiply the number of new complex semiconductors to be discovered for high zT thermoelectrics or other applications.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/j.joule.2017.11.005DOIArticle
http://www.sciencedirect.com/science/article/pii/S2542435117301769PublisherArticle
ORCID:
AuthorORCID
Ohno, Saneyuki0000-0001-8192-996X
Imasato, Kazuki0000-0001-7294-1780
Tamaki, Hiromasa0000-0002-4717-0272
Kang, Stephen Dongmin0000-0002-7491-7933
Kanno, Tsutomu0000-0001-5412-4410
Snyder, G. Jeffrey0000-0003-1414-8682
Alternate Title:Phase Boundary Mapping to Obtain n-type Mg3Sb2-Based Thermoelectrics
Additional Information:© 2017 Published by Elsevier Inc. Received 19 July 2017, Revised 4 October 2017, Accepted 8 November 2017, Available online 1 December 2017, Published: December 1, 2017. The authors would like to thank Prof. Vladan Stevanović of Colorado School of Mines for fruitful discussions regarding the defect formation energy calculation. This work was supported by the NASA Science Mission Directorate's Radioisotope Power Systems Thermoelectric Technology Development. This work made use of the IMSERC and EPIC facilities at Northwestern University, which has received support from the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF NNCI-1542205); the MRSEC program (NSF DMR-1121262) at the Materials Research Center; the State of Illinois and International Institute for Nanotechnology (IIN). Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract no. DE-AC02-06CH11357. P.G. and E.S.T. acknowledge NSF DMREF 1729594. G.J.S. acknowledges NSF DMREF 1729487. Author Contributions: S.O., S.D.K., and G.J.S. conceived and designed this research project; S.O. and K.I. carried out synthesis and characterizations at Northwestern University; H.T., H.K.S., and T.K. executed experiments at Panasonic; S.O. analyzed all the experimental data; S.A. performed phase diagram calculation; P.G. conducted DFT defect calculations; S.O., S.D.K., S.A., H.T., P.G., E.S.T., and G.J.S. prepared and edited the manuscript.
Funders:
Funding AgencyGrant Number
NASAUNSPECIFIED
NSFNNCI-1542205
NSFDMR-1121262
State of IllinoisUNSPECIFIED
International Institute for Nanotechnology (IIN)UNSPECIFIED
Department of Energy (DOE)DE-AC02-06CH11357
NSFDMR-1729594
NSFDMR-1729487
Subject Keywords:Saneyuki Ohno, Kazuki Imasato, Shashwat Anand, Hiromasa Tamaki, Stephen Dongmin Kang, Prashun Gorai, Hiroki K. Sato, Eric S. Toberer, Tsutomu Kanno, G. Jeffrey Snyder, Phase Boundary Mapping to Obtain n-type Mg3Sb2-Based Thermoelectrics, Joule, Volume 2, Issue 1, 2018, Pages 141-154, ISSN 2542-4351, https://doi.org/10.1016/j.joule.2017.11.005. (http://www.sciencedirect.com/science/article/pii/S2542435117301769)
Issue or Number:1
Record Number:CaltechAUTHORS:20171206-111345471
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20171206-111345471
Official Citation:Saneyuki Ohno, Kazuki Imasato, Shashwat Anand, Hiromasa Tamaki, Stephen Dongmin Kang, Prashun Gorai, Hiroki K. Sato, Eric S. Toberer, Tsutomu Kanno, G. Jeffrey Snyder, Phase Boundary Mapping to Obtain n-type Mg3Sb2-Based Thermoelectrics, Joule, Available online 1 December 2017, ISSN 2542-4351, https://doi.org/10.1016/j.joule.2017.11.005. (https://www.sciencedirect.com/science/article/pii/S2542435117301769)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:83729
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:07 Dec 2017 00:16
Last Modified:09 Mar 2020 13:19

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