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Use of Compatible Polymer Blends To Fabricate Arrays of Carbon Black−Polymer Composite Vapor Detectors

Doleman, Brett J. and Sanner, Robert D. and Severin, Erik J. and Grubbs, Robert H. and Lewis, Nathan S. (1998) Use of Compatible Polymer Blends To Fabricate Arrays of Carbon Black−Polymer Composite Vapor Detectors. Analytical Chemistry, 70 (13). pp. 2560-2564. ISSN 0003-2700. http://resolver.caltech.edu/CaltechAUTHORS:20180124-100638103

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Abstract

Compatible blends of poly(vinyl acetate) and poly(methyl methacrylate) have been used to produce a series of electrically conducting carbon black composites whose resistance is sensitive to the nature and concentration of an analyte in the vapor phase. The dc electrical resistance response of the composites was found to be a nonlinear function of the mole fraction of poly(vinyl acetate) in the blend. These compatible blend composite detectors provided additional analyte discrimination information relative to a reference detector array that only contained composites formed using the pure polymer phases. The added discrimination power provided by the compatible blend detectors, and thus the added diversity of the enhanced detector array, was quantified through use of a statistical metric to assess the performance of detector arrays in various vapor classification tasks.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ac971238hDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ac971238hPublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Lewis, Nathan S.0000-0001-5245-0538
Additional Information:© 1998 American Chemical Society. Received for review November 12, 1997. Accepted March 19, 1998. Publication Date (Web): May 13, 1998. We thank NASA, the Army Research Office (Grants DAAH04-96-1-0048 and DAAG55-97-1-0187), and DARPA for support of this work. B.J.D. acknowledges the NSERC Canada for a graduate fellowship, and R.D.S. acknowledges the University of California Lawrence Livermore National Laboratory for support from its Professional Research and Teaching Leave program while at Caltech.
Funders:
Funding AgencyGrant Number
Army Research Office (ARO)AAH04-96-1-0048
Army Research Office (ARO)DAAG55-97-1-0187
Defense Advanced Research Projects Agency (DARPA)UNSPECIFIED
Natural Sciences and Engineering Research Council of Canada (NSERC)UNSPECIFIED
Lawrence Livermore National LaboratoryUNSPECIFIED
Record Number:CaltechAUTHORS:20180124-100638103
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20180124-100638103
Official Citation:Use of Compatible Polymer Blends To Fabricate Arrays of Carbon Black−Polymer Composite Vapor Detectors. Brett J. Doleman, Robert D. Sanner, Erik J. Severin, Robert H. Grubbs, and and Nathan S. Lewis. Analytical Chemistry 1998 70 (13), 2560-2564. DOI: 10.1021/ac971238h
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:84500
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:25 Jan 2018 17:28
Last Modified:25 Jan 2018 17:28

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