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Organic Chemistry of C_(60) (Buckminsterfullerene): Chromatography and Osmylation

Hawkins, Joel M. and Lewis, Timothy A. and Loren, Stefan D. and Meyer, Axel and Heath, James R. and Shibato, Yoko and Saykally, Richard J. (1990) Organic Chemistry of C_(60) (Buckminsterfullerene): Chromatography and Osmylation. Journal of Organic Chemistry, 55 (26). pp. 6250-6252. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20180302-084837776

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Abstract

Treatment of CG0 with osmium tetroxide and pyridine gives the osmate ester (2.1 adduct) establishing that oxygen functionality can be added to C_(60) without disrupting the carbon framework.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jo00313a009DOIArticle
https://pubs.acs.org/doi/10.1021/jo00313a009PublisherArticle
ORCID:
AuthorORCID
Heath, James R.0000-0001-5356-4385
Additional Information:© 1990 American Chemical Society. Published in print 1 December 1990. J.M.H. is grateful to the National Science Foundation (Presidential Young Investigator Award, CHE-8857453), the Camille and Henry Dreyfus Foundation (New Faculty Grant), the Shell Oil Company Foundation (Shell Faculty Fellowship), Xerox Corporation, Monsanto Company, and the Merck Sharp & Dohme Research Laboratories for financial support. J.R.H. thanks the NASA SETI foundation and R.J.S. thanks the National Science Foundation for support. We thank Joseph Lyssikatos for assistance with the 13C NMR spectrum of C_(70).
Funders:
Funding AgencyGrant Number
NSFCHE-8857453
Camille and Henry Dreyfus FoundationUNSPECIFIED
Xerox CorporationUNSPECIFIED
Shell Oil Company FoundationUNSPECIFIED
Monsanto CompanyUNSPECIFIED
Merck Sharp & Dohme Research LaboratoriesUNSPECIFIED
SETI FoundationUNSPECIFIED
Issue or Number:26
Record Number:CaltechAUTHORS:20180302-084837776
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180302-084837776
Official Citation:Organic chemistry of C60 (buckminsterfullerene): chromatography and osmylation Joel M. Hawkins, Timothy A. Lewis, Stefan D. Loren, Axel Meyer, James R. Heath, Yoko Shibato, and Richard J. Saykally The Journal of Organic Chemistry 1990 55 (26), 6250-6252 DOI: 10.1021/jo00313a009
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85059
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:02 Mar 2018 21:54
Last Modified:03 Oct 2019 19:26

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