Organic Chemistry of C_(60) (Buckminsterfullerene): Chromatography and Osmylation

Hawkins, Joel M. and Lewis, Timothy A. and Loren, Stefan D. and Meyer, Axel and Heath, James R. and Shibato, Yoko and Saykally, Richard J. (1990) Organic Chemistry of C_(60) (Buckminsterfullerene): Chromatography and Osmylation. Journal of Organic Chemistry, 55 (26). pp. 6250-6252. ISSN 0022-3263. doi:10.1021/jo00313a009. https://resolver.caltech.edu/CaltechAUTHORS:20180302-084837776

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Abstract

Treatment of CG0 with osmium tetroxide and pyridine gives the osmate ester (2.1 adduct) establishing that oxygen functionality can be added to C_(60) without disrupting the carbon framework.

Item Type:

Article

Related URLs:

URL	URL Type	Description
http://dx.doi.org/10.1021/jo00313a009	DOI	Article
https://pubs.acs.org/doi/10.1021/jo00313a009	Publisher	Article

ORCID:

Author	ORCID
Heath, James R.	0000-0001-5356-4385

Additional Information:

© 1990 American Chemical Society. Published in print 1 December 1990. J.M.H. is grateful to the National Science Foundation (Presidential Young Investigator Award, CHE-8857453), the Camille and Henry Dreyfus Foundation (New Faculty Grant), the Shell Oil Company Foundation (Shell Faculty Fellowship), Xerox Corporation, Monsanto Company, and the Merck Sharp & Dohme Research Laboratories for financial support. J.R.H. thanks the NASA SETI foundation and R.J.S. thanks the National Science Foundation for support. We thank Joseph Lyssikatos for assistance with the 13C NMR spectrum of C_(70).

Funders:

Funding Agency	Grant Number
NSF	CHE-8857453
Camille and Henry Dreyfus Foundation	UNSPECIFIED
Xerox Corporation	UNSPECIFIED
Shell Oil Company Foundation	UNSPECIFIED
Monsanto Company	UNSPECIFIED
Merck Sharp & Dohme Research Laboratories	UNSPECIFIED
SETI Foundation	UNSPECIFIED

Issue or Number:

DOI:

10.1021/jo00313a009

Record Number:

CaltechAUTHORS:20180302-084837776

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20180302-084837776

Official Citation:

Organic chemistry of C60 (buckminsterfullerene): chromatography and osmylation Joel M. Hawkins, Timothy A. Lewis, Stefan D. Loren, Axel Meyer, James R. Heath, Yoko Shibato, and Richard J. Saykally The Journal of Organic Chemistry 1990 55 (26), 6250-6252 DOI: 10.1021/jo00313a009

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ID Code:

85059

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CaltechAUTHORS

Deposited By:

Ruth Sustaita

Deposited On:

02 Mar 2018 21:54

Last Modified:

15 Nov 2021 20:25

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