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Interactions between Conjugated Polymers and Single-Walled Carbon Nanotubes

Steuerman, David W. and Stark, Alexander and Narizzano, Riccardo and Choi, Hyeon and Ries, Ryan S. and Nicolini, Claudio and Stoddart, J. Fraser and Heath, James R. (2002) Interactions between Conjugated Polymers and Single-Walled Carbon Nanotubes. Journal of Physical Chemistry B, 106 (12). pp. 3124-3130. ISSN 1520-6106. https://resolver.caltech.edu/CaltechAUTHORS:20180302-095529176

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Abstract

The chemical interactions between single walled carbon nanotubes (SWNTs) and two structurally similar polymers, poly{(m-phenylenevinylene)-co-[(2,5-dioctyloxy-p-phenylene)vinylene]}, or PmPV, and poly{(2,6-pyridinylenevinylene)-co-[(2,5-dioctyloxy-p-phenylene)vinylene]}, or PPyPV, are investigated. The fundamental difference between these two polymers is that PPyPV is a base and is readily protonated via the addition of HCl. Both polymers promote chloroform solubilization of SWNTs. We find that the SWNT/PPyPV interaction lowers the pKa of PPyPV. Optoelectronic devices, fabricated from single polymer-wrapped SWNT structures, reveal a photogating effect on charge transport which can rectify or amplify current flow through the tubes. For PmPV wrapped tubes, the wavelength dependence of this effect correlates to the absorption spectrum of PmPV. For PPyPV, the wavelength dependence correlates with the absorption spectrum of protonated PPyPV, indicating that SWNTs assist in charge stabilization.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/jp014326lDOIArticle
https://pubs.acs.org/doi/abs/10.1021/jp014326lPublisherArticle
ORCID:
AuthorORCID
Stoddart, J. Fraser0000-0003-3161-3697
Heath, James R.0000-0001-5356-4385
Additional Information:© 2002 American Chemical Society. Received 27 November 2001. Published online 3 March 2002. Published in print 1 March 2002. This research was supported by the Office of Naval Research, the Semiconductor Research Corporation, and by the National Science Foundation. R.N. and C.N. acknowledge support from the Fondazione EI.B.A. and by Polo Nazionale Bioelettronica.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Semiconductor Research CorporationUNSPECIFIED
NSFUNSPECIFIED
Fondazione EI.B.A.UNSPECIFIED
Polo Nazionale BioelettronicaUNSPECIFIED
Issue or Number:12
Record Number:CaltechAUTHORS:20180302-095529176
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180302-095529176
Official Citation:Interactions between Conjugated Polymers and Single-Walled Carbon Nanotubes David W. Steuerman, Alexander Star, Riccardo Narizzano, Hyeon Choi, Ryan S. Ries, Claudio Nicolini, J. Fraser Stoddart, and James R. Heath The Journal of Physical Chemistry B 2002 106 (12), 3124-3130 DOI: 10.1021/jp014326l
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85063
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:02 Mar 2018 21:46
Last Modified:03 Oct 2019 19:26

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