Wu, Zhe and Grubbs, Robert H. (1994) Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene. Macromolecules, 27 (23). pp. 6700-6703. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20180313-143927774
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Abstract
Near monodispersed linear polyethylene can be synthesized y hydrogenation of polybutadiene prepared by the living ring-opening metathesis polymerization (ROMP) of cyclobutene. The polyethylene is highly crystalline, as determined by powder X-ray diffraction, and defect free, as shown by spectroscopic data. Living polycyclobutene can also react with anthracene dialdehyde to give a labeled polymer and with norbornene to produce a block copolymer.
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| Additional Information: | © 1994 American Chemical Society. Received June 1, 1994; Revised Manuscript Received August 8, 1994. We gratefully acknowledge the financial support from the National Science Foundation. | |||||||||
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| Issue or Number: | 23 | |||||||||
| Record Number: | CaltechAUTHORS:20180313-143927774 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180313-143927774 | |||||||||
| Official Citation: | Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene. Zhe Wu and Robert H. Grubbs. Macromolecules 1994 27 (23), 6700-6703. DOI: 10.1021/ma00101a002 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 85285 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 13 Mar 2018 22:46 | |||||||||
| Last Modified: | 03 Oct 2019 19:29 |
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