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Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene

Wu, Zhe and Grubbs, Robert H. (1994) Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene. Macromolecules, 27 (23). pp. 6700-6703. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20180313-143927774

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Abstract

Near monodispersed linear polyethylene can be synthesized y hydrogenation of polybutadiene prepared by the living ring-opening metathesis polymerization (ROMP) of cyclobutene. The polyethylene is highly crystalline, as determined by powder X-ray diffraction, and defect free, as shown by spectroscopic data. Living polycyclobutene can also react with anthracene dialdehyde to give a labeled polymer and with norbornene to produce a block copolymer.


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https://doi.org/10.1021/ma00101a002DOIArticle
https://pubs.acs.org/doi/abs/10.1021/ma00101a002PublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 1994 American Chemical Society. Received June 1, 1994; Revised Manuscript Received August 8, 1994. We gratefully acknowledge the financial support from the National Science Foundation.
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NSFUNSPECIFIED
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Caltech Arnold and Mabel Laboratories of Chemical Synthesis8953
Issue or Number:23
Record Number:CaltechAUTHORS:20180313-143927774
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180313-143927774
Official Citation:Synthesis of Narrow Dispersed Linear Polyethylene and Block Copolymers from Polycyclobutene. Zhe Wu and Robert H. Grubbs. Macromolecules 1994 27 (23), 6700-6703. DOI: 10.1021/ma00101a002
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85285
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:13 Mar 2018 22:46
Last Modified:03 Oct 2019 19:29

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