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New Vistas in Zeolite and Molecular Sieve Catalysis

Davis, Mark E. (1993) New Vistas in Zeolite and Molecular Sieve Catalysis. Accounts of Chemical Research, 26 (3). pp. 111-115. ISSN 0001-4842. doi:10.1021/ar00027a006. https://resolver.caltech.edu/CaltechAUTHORS:20180315-073126373

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Abstract

Zeolites and zeolite-like molecular sieves are able to recognize, discriminate, and organize molecules with precisions that can be less than 1 Å. Because these structures (Figure 1) contain uniformly sized pores in the range of 4-13 Å, they have been exploited by the petrochemical industries to perform many large-scale, shape-selective hydrocarbon reactions. Further information on the materials listed in Figure 1 is provided in Table I. The pore sizes listed are the crystallographic free diameters from each structure. Additionally, the dimensionality of the pore systems is provided. (A simple way to think about the dimensionality of the pore system is to place an organic molecule into the void space and observe in how many different directions it can move. For example, an n-hexane molecule can move in one direction in the channels of VPI-5 whereas it can travel in all three directions in NaX.) For more details on the structures of zeolites and molecular sieves, see ref 3.


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http://dx.doi.org/10.1021/ar00027a006DOIArticle
https://pubs.acs.org/doi/abs/10.1021/ar00027a006PublisherArticle
ORCID:
AuthorORCID
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 1993 American Chemical Society. Received July 17, 1992. I thank the many co-workers whose names appear on specific references for their invaluable contributions and acknowledge the generous financial support from numerous agencies and companies but most notably the National Science Foundation.
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Issue or Number:3
DOI:10.1021/ar00027a006
Record Number:CaltechAUTHORS:20180315-073126373
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180315-073126373
Official Citation:New vistas in zeolite and molecular sieve catalysis Mark E. Davis Accounts of Chemical Research 1993 26 (3), 111-115 DOI: 10.1021/ar00027a006
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85321
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Mar 2018 15:40
Last Modified:15 Nov 2021 20:27

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