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Reaction of chlorine nitrate with protonated water clusters: a model for heterogeneous reactions on polar stratospheric clouds

Nelson, Christine M. and Okumura, Mitchio (1992) Reaction of chlorine nitrate with protonated water clusters: a model for heterogeneous reactions on polar stratospheric clouds. Journal of Physical Chemistry, 96 (15). pp. 6112-6115. ISSN 0022-3654. doi:10.1021/j100194a003. https://resolver.caltech.edu/CaltechAUTHORS:20180315-140055191

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Abstract

We investigated the reactions of small protonated water clusters, H_3O^+(H_2O)_m, with chlorine nitrate, ClONO_2, to elucidate the molecular mechanism for the heterogeneous reaction of chlorine nitrate with ice. The ionic reaction products were various forms of protonated nitric acid, NO_2^+(H_2O)_m, m = 0, 1, 2. These products are analogous to products previously reported in the literature for the neutral reaction occurring on ice surfaces. Our results support the hypothesis that the heterogeneous reaction is acid-catalyzed.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/j100194a003DOIArticle
https://pubs.acs.org/doi/abs/10.1021/j100194a003PublisherArticle
ORCID:
AuthorORCID
Okumura, Mitchio0000-0001-6874-1137
Additional Information:© 1992 American Chemical Society. Acknowledgment is made to the National Science Foundation Presidential Young Investigator Award (Grant CHE-8957243) and to the Caltech Consortium in Chemistry and Chemical Engineering, founding members E. I. du Pont de Nemours and Co., Eastman Kodak Co., and Minnesota Mining and Manufacturing Inc. Additional support was provided by the Irvine Foundation, the Chevron Corp., a Dreyfus Newly Appointed Faculty Award, an AT & T Special Purpose Grant, and a Department of Education Graduate Fellowship (C.M.N.).
Funders:
Funding AgencyGrant Number
NSFCHE-8957243
CaltechUNSPECIFIED
E. I. du Pont de Nemours and CompanyUNSPECIFIED
Eastman Kodak CompanyUNSPECIFIED
Minnesota Mining and Manufacturing Inc.UNSPECIFIED
Irvine FoundationUNSPECIFIED
Chevron CorporationUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
AT&TUNSPECIFIED
Department of Education Graduate FellowshipUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Arthur Amos Noyes Laboratory of Chemical Physics8599
Issue or Number:15
DOI:10.1021/j100194a003
Record Number:CaltechAUTHORS:20180315-140055191
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180315-140055191
Official Citation:Reaction of chlorine nitrate with protonated water clusters: a model for heterogeneous reactions on polar stratospheric clouds. Christine M. Nelson and Mitchio Okumura. The Journal of Physical Chemistry 1992 96 (15), 6112-6115 DOI: 10.1021/j100194a003
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85342
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:26 Mar 2018 22:21
Last Modified:15 Nov 2021 20:27

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