Nelson, Christine M. and Okumura, Mitchio (1992) Reaction of chlorine nitrate with protonated water clusters: a model for heterogeneous reactions on polar stratospheric clouds. Journal of Physical Chemistry, 96 (15). pp. 6112-6115. ISSN 0022-3654. doi:10.1021/j100194a003. https://resolver.caltech.edu/CaltechAUTHORS:20180315-140055191
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Abstract
We investigated the reactions of small protonated water clusters, H_3O^+(H_2O)_m, with chlorine nitrate, ClONO_2, to elucidate the molecular mechanism for the heterogeneous reaction of chlorine nitrate with ice. The ionic reaction products were various forms of protonated nitric acid, NO_2^+(H_2O)_m, m = 0, 1, 2. These products are analogous to products previously reported in the literature for the neutral reaction occurring on ice surfaces. Our results support the hypothesis that the heterogeneous reaction is acid-catalyzed.
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| Additional Information: | © 1992 American Chemical Society. Acknowledgment is made to the National Science Foundation Presidential Young Investigator Award (Grant CHE-8957243) and to the Caltech Consortium in Chemistry and Chemical Engineering, founding members E. I. du Pont de Nemours and Co., Eastman Kodak Co., and Minnesota Mining and Manufacturing Inc. Additional support was provided by the Irvine Foundation, the Chevron Corp., a Dreyfus Newly Appointed Faculty Award, an AT & T Special Purpose Grant, and a Department of Education Graduate Fellowship (C.M.N.). | ||||||||||||||||||||||
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| Issue or Number: | 15 | ||||||||||||||||||||||
| DOI: | 10.1021/j100194a003 | ||||||||||||||||||||||
| Record Number: | CaltechAUTHORS:20180315-140055191 | ||||||||||||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180315-140055191 | ||||||||||||||||||||||
| Official Citation: | Reaction of chlorine nitrate with protonated water clusters: a model for heterogeneous reactions on polar stratospheric clouds. Christine M. Nelson and Mitchio Okumura. The Journal of Physical Chemistry 1992 96 (15), 6112-6115 DOI: 10.1021/j100194a003 | ||||||||||||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||||||||||||
| ID Code: | 85342 | ||||||||||||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||||||||||||
| Deposited On: | 26 Mar 2018 22:21 | ||||||||||||||||||||||
| Last Modified: | 15 Nov 2021 20:27 |
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