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Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis

Chatterjee, Arnab K. and Grubbs, Robert H. (1999) Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis. Organic Letters, 1 (11). pp. 1751-1753. ISSN 1523-7060. doi:10.1021/ol991023p. https://resolver.caltech.edu/CaltechAUTHORS:20180320-101056334

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Abstract

Trisubstituted alkenes have been prepared for the first time via intermolecular olefin cross-metathesis, using 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium alkylidene complexes 3a,b in good yields with moderate E selectivity. In addition, protected alcohols near the geminal disubstituted olefin improve reactivity for cross-metathesis.


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https://doi.org/10.1021/ol991023pDOIArticle
https://pubs.acs.org/doi/abs/10.1021/ol991023pPublisherArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 1999 American Chemical Society. Received September 7, 1999. Publication Date (Web): November 2, 1999. Support has been generously provided by the National Institutes of Health. The authors thank Andrew G. Myers, Matthias Scholl, Thomas A. Kirkland, Helen E. Blackwell, and Daniel J. O'Leary for useful discussions and encouragement. The authors also wish to thank Richard Pederson for a generous supply of compound 8.
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Issue or Number:11
DOI:10.1021/ol991023p
Record Number:CaltechAUTHORS:20180320-101056334
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180320-101056334
Official Citation:Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis. Arnab K. Chatterjee and Robert H. Grubbs. Organic Letters 1999 1 (11), 1751-1753. DOI: 10.1021/ol991023p
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85375
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:02 Apr 2018 18:37
Last Modified:15 Nov 2021 20:28

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