Chatterjee, Arnab K. and Grubbs, Robert H. (1999) Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis. Organic Letters, 1 (11). pp. 1751-1753. ISSN 1523-7060. doi:10.1021/ol991023p. https://resolver.caltech.edu/CaltechAUTHORS:20180320-101056334
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Abstract
Trisubstituted alkenes have been prepared for the first time via intermolecular olefin cross-metathesis, using 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene ruthenium alkylidene complexes 3a,b in good yields with moderate E selectivity. In addition, protected alcohols near the geminal disubstituted olefin improve reactivity for cross-metathesis.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1999 American Chemical Society. Received September 7, 1999. Publication Date (Web): November 2, 1999. Support has been generously provided by the National Institutes of Health. The authors thank Andrew G. Myers, Matthias Scholl, Thomas A. Kirkland, Helen E. Blackwell, and Daniel J. O'Leary for useful discussions and encouragement. The authors also wish to thank Richard Pederson for a generous supply of compound 8. | |||||||||
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| Issue or Number: | 11 | |||||||||
| DOI: | 10.1021/ol991023p | |||||||||
| Record Number: | CaltechAUTHORS:20180320-101056334 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180320-101056334 | |||||||||
| Official Citation: | Synthesis of Trisubstituted Alkenes via Olefin Cross-Metathesis. Arnab K. Chatterjee and Robert H. Grubbs. Organic Letters 1999 1 (11), 1751-1753. DOI: 10.1021/ol991023p | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 85375 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 02 Apr 2018 18:37 | |||||||||
| Last Modified: | 15 Nov 2021 20:28 |
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