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A Chromium Hydroxide/MIL-101(Cr) MOF Composite Catalyst and Its Use for the Selective Isomerization of Glucose to Fructose

Guo, Qiang and Ren, Limin and Kumar, Prashant and Cybulskis, Viktor J. and Mkhoyan, K. Andre and Davis, Mark E. and Tsapatsis, Michael (2018) A Chromium Hydroxide/MIL-101(Cr) MOF Composite Catalyst and Its Use for the Selective Isomerization of Glucose to Fructose. Angewandte Chemie International Edition, 57 (18). pp. 4926-4930. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20180402-084148907

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Abstract

A metal–organic framework (MOF)‐based catalyst, chromium hydroxide/MIL‐101(Cr), was prepared by a one‐pot synthesis method. The combination of chromium hydroxide particles on and within Lewis acidic MIL‐101 accomplishes highly selective conversion of glucose to fructose in the presence of ethanol, matching the performance of optimized Sn‐containing Lewis acidic zeolites. Differently from zeolites, NMR spectroscopy studies with isotopically labeled molecules demonstrate that isomerization of glucose to fructose on this catalyst, proceeds predominantly via a proton transfer mechanism.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1002/anie.201712818DOIArticle
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201712818PublisherArticle
ORCID:
AuthorORCID
Davis, Mark E.0000-0001-8294-1477
Tsapatsis, Michael0000-0001-5610-3525
Additional Information:© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. Manuscript received: December 13, 2017; Accepted manuscript online: February 28, 2018; Version of record online: March 22, 2018. This work was supported as part of the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award DE-SC0001004. The authors declare no conflict of interest.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-SC0001004
Subject Keywords:chromium hydroxide; fructose; heterogeneous catalysis; isomerization; metal–organic frameworks
Issue or Number:18
Record Number:CaltechAUTHORS:20180402-084148907
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180402-084148907
Official Citation:Q. Guo, L. Ren, P. Kumar, V. J. Cybulskis, K. A. Mkhoyan, M. E. Davis, M. Tsapatsis, Angew. Chem. Int. Ed. 2018, 57, 4926.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85554
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:02 Apr 2018 16:00
Last Modified:09 Mar 2020 13:19

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