Thiel, Patricia A. and Weinberg, W. Henry (1980) An Electron Energy Loss Spectroscopic Investigation of the Adsorption of Nitric Oxide, Carbon Monoxide, and Hydrogen on the Basal Plane of Ruthenium. In: Vibrational Spectroscopies for Adsorbed Species. ACS Symposium Series. No.137. American Chemical Society , Washington, DC, pp. 191-215. ISBN 9780841205857. https://resolver.caltech.edu/CaltechAUTHORS:20180404-131147789
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Abstract
The study of the adsorption of nitric oxide on the surfaces of Group VIII transition metals is relevant to several major catalytic processes. Among these are the oxidation of ammonia to nitric oxide and subsequent synthesis of nitric acid, and the environmentally important removal of nitric oxide from exhaust stream effluents (3). The latter process involves dissociation of NO and requires the presence of a reducing agent, e.g., CO or H_2, to remove oxygen from the catalyst surface and thus prevent its being poisoned (3). Ruthenium is unique among the noble metals in its strong selectivity for formation of N_2 as a decomposition product of NO at relatively low temperatures, i.e., less than 800 K.
| Item Type: | Book Section | |||||||||
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| Additional Information: | © 1980 American Chemical Society. Received July 31, 1979. Published in print 26 November 1980. It is a pleasure to acknowledge the contributions of our coworkers, Dr. Glenn E. Thomas and Dr. John T. Yates, Jr. This work was supported by the National Science Foundation under Grant No. CHE77-16314. | |||||||||
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| Series Name: | ACS Symposium Series | |||||||||
| Issue or Number: | 137 | |||||||||
| DOI: | 10.1021/bk-1980-0137.ch010 | |||||||||
| Record Number: | CaltechAUTHORS:20180404-131147789 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180404-131147789 | |||||||||
| Official Citation: | An Electron Energy Loss Spectroscopic Investigation of the Adsorption of Nitric Oxide, Carbon Monoxide, and Hydrogen on the Basal Plane of Ruthenium PATRICIA A. THIEL and W. HENRY WEINBERG Vibrational Spectroscopies for Adsorbed Species. November 26, 1980 , 191-215 DOI:10.1021/bk-1980-0137.ch010 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 85608 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 04 Apr 2018 22:03 | |||||||||
| Last Modified: | 15 Nov 2021 20:30 |
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