Darensbourg, Donald J. and Gibson, Guy (1987) New Methods for Acquiring IR Spectral Data in Organometallic Chemistry and Catalysis. In: Experimental Organometallic Chemistry. ACS Symposium Series. No.357. American Chemical Society , Washington, DC, pp. 230-256. ISBN 9780841214385. https://resolver.caltech.edu/CaltechAUTHORS:20180405-083033875
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Abstract
The advent of new infrared sampling accessories has allowed in situ study of organometallic systems under conditions that were previously not readily accessible. The techniques of Cylindrical Internal Reflectance (CIR) and Diffuse Reflectance spectroscopies are described herein. The CIR phenomenon was employed in three different apparatus. Two different high pressure CIR cells were used to study reactions homogeneously catalyzed by [μ-HW_2(CO)_(10)]^-. Low temperature reactions of Mo and W complexes were studied using an ambient pressure CIR cell. The diffuse reflectance technique was employed to study powdered samples of Ru carbonyl complexes supported on Al_2O_3.
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| Additional Information: | © 1987 American Chemical Society. Received September 14, 1987. We are most appreciative to Spectra Tech Inc., 652 Glenbrook Road, P. 0. Box 2215, Stamford, CT 06906 for their generous support of our research efforts. We thank Siegfried Jenner, Erich Siegel, and Gabor Faludi of the Caltech Glass Shop for their assistance. Our research in inorganic photochemistry is supported by the National Science Foundation. This is Contribution No. 7486 from the Arthur Amos Noyes Laboratory. | |||||||||
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| Series Name: | ACS Symposium Series | |||||||||
| Issue or Number: | 357 | |||||||||
| DOI: | 10.1021/bk-1987-0357.ch009 | |||||||||
| Record Number: | CaltechAUTHORS:20180405-083033875 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180405-083033875 | |||||||||
| Official Citation: | New Methods for Acquiring IR Spectral Data in Organometallic Chemistry and Catalysis Donald J. Darensbourg and Guy Gibson Experimental Organometallic Chemistry. November 24, 1987 , 230-256 DOI:10.1021/bk-1987-0357.ch009 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 85628 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 05 Apr 2018 21:03 | |||||||||
| Last Modified: | 15 Nov 2021 20:30 |
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