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New Polymeric Materials with Cubic Optical Nonlinearities Derived from Ring-Opening Metathesis Polymerization

Grubbs, R. H. and Gorman, C. B. and Ginsburg, E. J. and Perry, Joseph W. and Marder, Seth R. (1991) New Polymeric Materials with Cubic Optical Nonlinearities Derived from Ring-Opening Metathesis Polymerization. In: Materials for Nonlinear Optics. ACS Symposium Series. No.455. American Chemical Society , Washington, DC, pp. 672-682. https://resolver.caltech.edu/CaltechAUTHORS:20180405-124959676

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Abstract

Partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. Certain poly-COT derivatives afford soluble, highly conjugated poly acetylenes. These materials exhibit large third-order optical nonlinearities and low scattering losses.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/bk-1991-0455.ch045DOIArticle
https://pubs.acs.org/doi/abs/10.1021/bk-1991-0455.ch045PublisherArticle
ORCID:
AuthorORCID
Grubbs, R. H.0000-0002-0057-7817
Additional Information:© 1991 American Chemical Society. Received August 2, 1990. Published in print 11 March 1991. The research described in this paper was performed, in part, by the Jet Propulsion Laboratory, California Institute of Technology as part of its Center for Space Microelectronics Technology which is supported by the Strategic Defense Initiative Organization, Innovative Science and Technology Office through an agreement with the National Aeronautics and Space Administration (NASA). RHG acknowledges financial support from the Office of Naval Research. SRM thanks the National Research Council and NASA for a Resident Research Associateship at JPL. EJG thanks IBM for a research fellowship. CBG thanks the JPL for a research fellowship. The authors thank Dr. L. Khundkar, B. G. Tiemann and K. J. Perry for technical assistance.
Funders:
Funding AgencyGrant Number
Strategic Defense Initiative Organization (SDIO)UNSPECIFIED
NASAUNSPECIFIED
National Research CouncilUNSPECIFIED
IBMUNSPECIFIED
Series Name:ACS Symposium Series
Issue or Number:455
Record Number:CaltechAUTHORS:20180405-124959676
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180405-124959676
Official Citation:New Polymeric Materials with Cubic Optical Nonlinearities Derived from Ring-Opening Metathesis Polymerization R. H. Grubbs, C. B. Gorman, E. J. Ginsburg, Joseph W. Perry, and Seth R. Marder Materials for Nonlinear Optics. March 11, 1991, 672-682 DOI:10.1021/bk-1991-0455.ch045
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85639
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:05 Apr 2018 20:20
Last Modified:03 Oct 2019 19:33

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