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Selective Oxidation of Alkanes, Alkenes, and Phenol with Aqueous H_2O_2 on Titanium Silicate Molecular Sieves

Khouw, C. B. and Li, H. X. and Dartt, C. B. and Davis, M. E. (1993) Selective Oxidation of Alkanes, Alkenes, and Phenol with Aqueous H_2O_2 on Titanium Silicate Molecular Sieves. In: Catalytic Selective Oxidation. ACS Symposium Series. No.523. American Chemical Society , Washington, DC, pp. 273-280. ISBN 9780841226371. https://resolver.caltech.edu/CaltechAUTHORS:20180405-140055751

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Abstract

Titanium containing pure-silica ZSM-5 (TS-1) materials are synthesized using different methods. The activity of the titanium containing catalysts for the oxidation of alkanes, alkenes and phenol at temperatures below 100 °C using aqueous H_2O_2 as oxidant is reported. The relationships between the physicochemical and catalytic properties of these titanium silicates are discussed. The effects of added aluminum and sodium on the catalytic activity of TS-1 are described. The addition of sodium during the synthesis of TS-1 is detrimental to the catalytic activity while sodium incorporation into preformed TS-1 is not. The framework substitution of aluminum for silicon appears to decrease the amount of framework titanium.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/bk-1993-0523.ch020DOIArticle
https://pubs.acs.org/doi/abs/10.1021/bk-1993-0523.ch020PublisherArticle
ORCID:
AuthorORCID
Davis, M. E.0000-0001-8294-1477
Additional Information:© 1993 American Chemical Society. Received November 6, 1992. Published in print 5 May 1993. Support of this work was provided by the Amoco Oil Co. We thank Dr. S. M. Kuznicki for providing a sample of ETS-10 and Dr. R. J. Davis for recording the UVVIS diffuse reflectance spectrum of TS-1 samples.
Funders:
Funding AgencyGrant Number
Amoco Oil Co.UNSPECIFIED
Series Name:ACS Symposium Series
Issue or Number:523
DOI:10.1021/bk-1993-0523.ch020
Record Number:CaltechAUTHORS:20180405-140055751
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180405-140055751
Official Citation:Selective Oxidation of Alkanes, Alkenes, and Phenol with Aqueous H2O2 on Titanium Silicate Molecular Sieves C. B. Khouw, H. X. Li, C. B. Dartt, and M. E. Davis Catalytic Selective Oxidation. May 5, 1993, 273-280 DOI:10.1021/bk-1993-0523.ch020
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85650
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:05 Apr 2018 22:03
Last Modified:15 Nov 2021 20:30

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