Mesoscale trumps nanoscale: metallic mesoscale contact morphology for improved light trapping, optical absorption and grid conductance in silicon solar cells

Abstract

We report on a computational study exploring the design of mesoscale metallic front contacts for solar cells. We investigated silver contact structures with circle, triangle and square cross-sections for various length scales and surface coverages. We found that for ‘nanoscale’ contacts with widths between 10 nm and 1000 nm, resonant coupling actually impairs light absorption in the semiconductor. Conversely, for ‘mesoscale’ contact widths > 1000 nm, the light interaction is determined by the geometric shadowing. We find that mesoscale silver contacts with triangular cross-section outperform other nanostructure morphologies in reducing shadow losses and yield contact transparency of >99% percent with sheet resistance <0.2 Ω/sq. Surprisingly, very densely spaced mesoscale silver triangular cross-section contacts can enhance the absorption of thin silicon/silver structures by up to 15% at a front contact coverage of 83%, due to light trapping by the front contact. Such structures can also maintain up to 100% absorption within the silicon, at a front contact coverage of 50%, relative to the same structure without metal.