Bercaw, John E. (2018) Olefin trimerization and ethylene tandem conversion to linear low density polyethylene. In: 255th American Chemical Society National Meeting & Exposition, March 18-22, 2018, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20180413-141330194
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Abstract
Supporting a titanium catalyst (FI)TiCl_3 (FI = (N-(5-methyl-3-(1-adamantyl)salicylidene)-2'-(2"-methoxyphenyl) anilinato) onto MAO/silica affords a more active catalytic system for ethylene and 1-olefin trimerization. Cosupporting the (FI)TiCl_3 catalyst with the ethylene polymn. catalyst (CpSiNR)TiCl_2 (CpSiNR = (C5Me4) SiMe_2NCMe_3), either on sep. or the same MAO/silica particles, affords a catalyst system for producing butyl-branched LLDPE from and ethylene-only feed. Recent expts. aimed at defining the mechanism and LLDPE structure will be described.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2018 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20180413-141330194 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180413-141330194 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 85844 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 13 Apr 2018 21:22 | ||||||
| Last Modified: | 03 Oct 2019 19:36 |
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