Fu, Gregory C. (2018) Award Address (Herbert C. Brown Award for Creative Research in Synthetic Methods sponsored by the Purdue Borane Research Fund and the Herbert C. Brown Award Endowment). Nucleophilic substitution reactions: A radical alternative to S_N1 and S_N2 reactions. In: 255th American Chemical Society National Meeting & Exposition, March 18-22, 2018, New Orleans, LA. https://resolver.caltech.edu/CaltechAUTHORS:20180413-142635264
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Abstract
Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (S_N1 and S_N2) have limited scope and are not generally amenable to enantioselective variants that employ readily available racemic electrophiles. In this presentation, we will describe how the combination of radical chem. and transition-metal catalysis has opened the door to addressing the challenges of reactivity and of enantioselectivity in nucleophilic substitution reactions of secondary and tertiary alkyl electrophiles.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2018 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20180413-142635264 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180413-142635264 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 85845 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 13 Apr 2018 21:34 | ||||||
| Last Modified: | 03 Oct 2019 19:36 |
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