Luinstra, Gerrit A. and Wang, Lin and Stahl, Shannon S. and Labinger, Jay A. and Bercaw, John E. (1994) Oxidation of Zeise's Salt by [PtCl_6]^(2-): A Mechanistic Model for Hydrocarbon Oxidation. Organometallics, 13 (3). pp. 755-756. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20180413-142737272
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Abstract
Among a variety of organometallic approaches to C-H bond activation, reactions with electrophilic metal centers such as Pt(II), Pd(II), and Hg(Il) currently appear to offer the best prospects for productive alkane functionalization. Our working mechanistic scheme for conversion of alkanes to alcohols and alkyl chlorides by aqueous solutions of [PtCl_4]^(2-) and [PtCl_6]^(2-) (eq 1) consists of electrophilic C-H activation to generate a platinum(II) alkyl, transformation to a platinum(IV) alkyl, and nucleophilic attack by water or chloride, displacing platinum(II) and generating the product alcohol or alkyl chloride.
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| Alternate Title: | Oxidation of Zeise's Salt by [PtCl6]2-: A Mechanistic Model for Hydrocarbon Oxidation | ||||||||
| Additional Information: | © 1994 American Chemical Society. Received December 14, 1993. This work was supported by the Office of Naval Research and by Texaco Inc. S.S.S. thanks the National Science Foundation for a predoctoral fellowship. | ||||||||
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| Issue or Number: | 3 | ||||||||
| Record Number: | CaltechAUTHORS:20180413-142737272 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180413-142737272 | ||||||||
| Official Citation: | Oxidation of Zeise's Salt by [PtCl6]2-: A Mechanistic Model for Hydrocarbon Oxidation Gerrit A. Luinstra, Lin Wang, Shannon S. Stahl, Jay A. Labinger, and John E. Bercaw Organometallics 1994 13 (3), 755-756 DOI: 10.1021/om00015a005 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 85846 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | George Porter | ||||||||
| Deposited On: | 13 Apr 2018 21:37 | ||||||||
| Last Modified: | 12 Feb 2020 23:10 |
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