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Oxidation of Zeise's Salt by [PtCl_6]^(2-): A Mechanistic Model for Hydrocarbon Oxidation

Luinstra, Gerrit A. and Wang, Lin and Stahl, Shannon S. and Labinger, Jay A. and Bercaw, John E. (1994) Oxidation of Zeise's Salt by [PtCl_6]^(2-): A Mechanistic Model for Hydrocarbon Oxidation. Organometallics, 13 (3). pp. 755-756. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20180413-142737272

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Abstract

Among a variety of organometallic approaches to C-H bond activation, reactions with electrophilic metal centers such as Pt(II), Pd(II), and Hg(Il) currently appear to offer the best prospects for productive alkane functionalization. Our working mechanistic scheme for conversion of alkanes to alcohols and alkyl chlorides by aqueous solutions of [PtCl_4]^(2-) and [PtCl_6]^(2-) (eq 1) consists of electrophilic C-H activation to generate a platinum(II) alkyl, transformation to a platinum(IV) alkyl, and nucleophilic attack by water or chloride, displacing platinum(II) and generating the product alcohol or alkyl chloride.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/om00015a005DOIArticle
ORCID:
AuthorORCID
Stahl, Shannon S.0000-0002-9000-7665
Labinger, Jay A.0000-0002-1942-9232
Alternate Title:Oxidation of Zeise's Salt by [PtCl6]2-: A Mechanistic Model for Hydrocarbon Oxidation
Additional Information:© 1994 American Chemical Society. Received December 14, 1993. This work was supported by the Office of Naval Research and by Texaco Inc. S.S.S. thanks the National Science Foundation for a predoctoral fellowship.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Texaco Inc.UNSPECIFIED
NSF Predoctoral FellowshipUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arnold and Mabel Beckman Laboratories of Chemical Synthesis8903
Issue or Number:3
Record Number:CaltechAUTHORS:20180413-142737272
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180413-142737272
Official Citation:Oxidation of Zeise's Salt by [PtCl6]2-: A Mechanistic Model for Hydrocarbon Oxidation Gerrit A. Luinstra, Lin Wang, Shannon S. Stahl, Jay A. Labinger, and John E. Bercaw Organometallics 1994 13 (3), 755-756 DOI: 10.1021/om00015a005
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:85846
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:13 Apr 2018 21:37
Last Modified:12 Feb 2020 23:10

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