Pritchett, Beau P. and Stoltz, Brian M. (2018) Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids. Natural Product Reports, 35 (6). pp. 559-574. ISSN 0265-0568. PMCID PMC6013405. doi:10.1039/c7np00069c. https://resolver.caltech.edu/CaltechAUTHORS:20180416-135313177
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Abstract
Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocontrolled syntheses of Aspidosperma and related monoterpene indole alkaloids.
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Additional Information: | © 2018 The Royal Society of Chemistry. The article was received on 23 Dec 2017 and first published on 16 Apr 2018. The authors wish to thank NIH-NIGMS (R01GM080269), Amgen, the Gordon and Betty Moore Foundation, and Caltech for financial support. B. P. P. thanks the NSF for a predoctoral fellowship (Grant DGE-1144469). Dr Robert Allen Craig, II, is thanked for editorial assistance. The authors declare no conflicts of interest. | ||||||||||||
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Issue or Number: | 6 | ||||||||||||
PubMed Central ID: | PMC6013405 | ||||||||||||
DOI: | 10.1039/c7np00069c | ||||||||||||
Record Number: | CaltechAUTHORS:20180416-135313177 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180416-135313177 | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 85877 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Tony Diaz | ||||||||||||
Deposited On: | 16 Apr 2018 21:01 | ||||||||||||
Last Modified: | 09 Mar 2022 19:08 |
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