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Crystal structure and equation of state of Fe-Si alloys at super-Earth core conditions

Wicks, June K. and Smith, Raymond F. and Fratanduono, Dayne E. and Coppari, Federica and Kraus, Richard G. and Newman, Matthew G. and Rygg, J. Ryan and Eggert, Jon H. and Duffy, Thomas S. (2018) Crystal structure and equation of state of Fe-Si alloys at super-Earth core conditions. Science Advances, 4 (4). Art. No. eaao5864. ISSN 2375-2548. PMCID PMC5916515. https://resolver.caltech.edu/CaltechAUTHORS:20180425-170329736

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Abstract

The high-pressure behavior of Fe alloys governs the interior structure and dynamics of super-Earths, rocky extrasolar planets that could be as much as 10 times more massive than Earth. In experiments reaching up to 1300 GPa, we combine laser-driven dynamic ramp compression with in situ x-ray diffraction to study the effect of composition on the crystal structure and density of Fe-Si alloys, a potential constituent of super-Earth cores. We find that Fe-Si alloy with 7 weight % (wt %) Si adopts the hexagonal close-packed structure over the measured pressure range, whereas Fe-15wt%Si is observed in a body-centered cubic structure. This study represents the first experimental determination of the density and crystal structure of Fe-Si alloys at pressures corresponding to the center of a ~3–Earth mass terrestrial planet. Our results allow for direct determination of the effects of light elements on core radius, density, and pressures for these planets.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1126/sciadv.aao5864DOIArticle
http://advances.sciencemag.org/cgi/content/full/4/4/eaao5864/DC1PublisherSupplementary Materials
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5916515PubMed CentralArticle
ORCID:
AuthorORCID
Kraus, Richard G.0000-0003-2752-0121
Newman, Matthew G.0000-0003-3088-1892
Additional Information:© 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license, which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited. Received for publication August 5, 2017. Accepted for publication March 2, 2018. We thank the Omega Laser operations staff and the Target Engineering Team at Lawrence Livermore National Laboratory (LLNL) for assistance in these experiments. We acknowledge M. Millot (LLNL) for the helpful comments on the use of the Hyades hydrocode and C. Unterborn (Arizona State University) for providing an early version of the Planet Builder module within the BurnMan software. The research was supported by National Nuclear Security Administration through the National Laser Users’ Facility Program (contract nos. DE-NA0002154 and DE-NA0002720) and the Laboratory Directed Research and Development Program at LLNL (project no. 15-ERD-012). This work was performed under the auspices of the U.S. Department of Energy by LLNL (contract no. DE-AC52-07NA27344). Author contributions: J.K.W. and R.F.S. were responsible for the design and execution of the experiments. D.E.F. developed the backward characteristics analysis for pressure determination. J.H.E. and J.R.R. developed the analysis tools for PXRDIP image processing. J.K.W., R.F.S., F.C., R.G.K., M.G.N., and T.S.D. carried out the experiments. All authors were involved in discussions related to experimental design and data analysis. The authors declare that they have no competing interests. Data and materials availability: All data needed to evaluate the conclusions in the paper are present in the paper and/or the Supplementary Materials. Additional data related to this paper may be requested from the authors.
Funders:
Funding AgencyGrant Number
National Nuclear Security AdministrationDE-NA0002154
National Nuclear Security AdministrationDE-NA0002720
Lawrence Livermore National Laboratory15-ERD-012
Department of Energy (DOE)DE-AC52-07NA27344
Issue or Number:4
PubMed Central ID:PMC5916515
Record Number:CaltechAUTHORS:20180425-170329736
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180425-170329736
Official Citation:Crystal structure and equation of state of Fe-Si alloys at super-Earth core conditions BY JUNE K. WICKS, RAYMOND F. SMITH, DAYNE E. FRATANDUONO, FEDERICA COPPARI, RICHARD G. KRAUS, MATTHEW G. NEWMAN, J. RYAN RYGG, JON H. EGGERT, THOMAS S. DUFFY Science Advances 25 Apr 2018: Vol. 4, no. 4, eaao5864 DOI: 10.1126/sciadv.aao5864
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86055
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:26 Apr 2018 18:30
Last Modified:09 Mar 2020 13:19

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