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Experimental Formulation of Photonic Crystal Properties for Hierarchically Self-Assembled POSS–Bottlebrush Block Copolymers

Chae, Chang-Geun and Yu, Yong-Guen and Seo, Ho-Bin and Kim, Myung-Jin and Grubbs, Robert H. and Lee, Jae-Suk (2018) Experimental Formulation of Photonic Crystal Properties for Hierarchically Self-Assembled POSS–Bottlebrush Block Copolymers. Macromolecules, 51 (9). pp. 3458-3466. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20180426-143217615

[img] PDF (Experimental details, NMR spectra of compounds, solubility parameters and refractive indices of octaisobutyl POSS and PBzMA, and thermogravimetric analysis (TGA) thermograms of NB-A16-POSS, P(NB-A16-POSS), P(NB-g-BzMA), and P(NB-A16-POSS)-b-P(NB-g-BzMA)..) - Supplemental Material
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Abstract

Rodlike “POSS–bottlebrush block copolymers” (POSSBBCPs) containing crystalline polyhedral oligomeric silsesquioxane (POSS) pendants in A block and amorphous polymeric grafts in B block were utilized to create one-dimensional (1D) photonic crystals (PCs). 3-(12-(cis-5-Norbornene-exo-2,3-dicarboximido)dodecanoylamino)propylheptaisobutyl POSS (NB-A16-POSS, MA) and exo-5-norbornene-2-carbonyl-end poly(benzyl methacrylate) (NBPBzMA, MB) were employed in sequential ring-opening metathesis polymerization to afford poly[3-(12-(cis-5-norbornene-exo-2,3-dicarboximido)dodecanoylamino)propylheptaisobutyl POSS]-block-poly(exo-5-norbornene-2-carbonylate-graft-benzyl methacrylate)s, P(NB-A16-POSS)-b-P(NB-g-BzMA)s, with well-modulated block compositions (fA = 34, 50, and 67 wt %) and overall degrees of polymerization (DP = 323–939). The P(NB-A16-POSS)-b-P(NB-g-BzMA)s hierarchically self-assembled to form highly ordered 1D PC films with periodic lamellar arrays that can reflect visible light with particular wavelengths. Their reflectance bandwidths, reflectivities, and ranges of peak reflectance wavelnegth (λ_(peak)) were largely dependent on the block composition. The 1D PC films based on lamellar P(NB-A16-POSS)-b-P(NB-g-BzMA)s demonstrated the capability of formaulation of λ_(peak) as linear functions of initial polymerization parameter ([M]_0/[I]_0).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/acs.macromol.8b00298DOIArticle
https://pubs.acs.org/doi/suppl/10.1021/acs.macromol.8b00298PublisherSupporting Information
ORCID:
AuthorORCID
Chae, Chang-Geun0000-0001-8805-6743
Grubbs, Robert H.0000-0002-0057-7817
Lee, Jae-Suk0000-0002-6611-2801
Additional Information:© 2018 American Chemical Society. Received: February 7, 2018. Revised: April 2, 2018. This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF), funded by the Ministry of Science, ICT and Future Planning (NRF-2015R1A2A1A01002493). This work was also supported by GIST Research Institute (GRI) grant funded by the GIST in 2018. We thank Ji-Hyun Lee, Dr. Wonjin Moon, and Dr. Youn-Joong Kim in Korea Basic Science Institute (KBSI) for supporting the preparation of FIB samples. The authors declare no competing financial interest.
Funders:
Funding AgencyGrant Number
National Research Foundation of KoreaNRF-2015R1A2A1A01002493
GIST Research Institute (GRI)UNSPECIFIED
Issue or Number:9
Record Number:CaltechAUTHORS:20180426-143217615
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180426-143217615
Official Citation:Experimental Formulation of Photonic Crystal Properties for Hierarchically Self-Assembled POSS–Bottlebrush Block Copolymers. Chang-Geun Chae, Yong-Guen Yu, Ho-Bin Seo, Myung-Jin Kim, Robert H. Grubbs, and Jae-Suk Lee. Macromolecules 2018 51 (9), 3458-3466. DOI: 10.1021/acs.macromol.8b00298
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86066
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:27 Apr 2018 16:16
Last Modified:03 Oct 2019 19:39

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