Gunnoe, T. and Groves, John and Goddard, William and Schwartz, Nichole and Boaz, Nicholas and Fu, Ross and Nielsen, Robert and Fortman, George and Kalman, Steven (2017) Partial oxidation of light alkanes by iodine oxides. In: 254th American Chemical Society National Meeting & Exposition, August 20-24, 2017, Washington, DC. https://resolver.caltech.edu/CaltechAUTHORS:20180501-151359348
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Abstract
The selective and low temp. conversion of light alkanes to functionalized products has been a long- standing challenge. In protic media, the reaction of light alkanes (methane, ethane, propane) with iodine oxides results in the conversion to monofunctionalized products. The transformations are effective over a broad range of temps. (100 - 235 degrees C) and pressures (240- 6900 kPa) in non- superacidic media. Alkane conversions between 15 % and 40 % with selectivity for mono- functionalized products between 85 % and 95 % have been achieved. The presentation will focus on results from alkane conversion as well as mechanistic studies.
| Item Type: | Conference or Workshop Item (Paper) | ||||||||||
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| Additional Information: | © 2017 American Chemical Society. | ||||||||||
| Record Number: | CaltechAUTHORS:20180501-151359348 | ||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180501-151359348 | ||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
| ID Code: | 86162 | ||||||||||
| Collection: | CaltechAUTHORS | ||||||||||
| Deposited By: | Tony Diaz | ||||||||||
| Deposited On: | 01 May 2018 22:28 | ||||||||||
| Last Modified: | 03 Oct 2019 19:40 |
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