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Second-order optical nonlinearities and photostabilities of 2-N-methylstilbazolium salts

Marder, Seth R. and Perry, Joseph W. and Tiemann, Bruce G. and Marsh, Richard E. and Schaefer, William P. (1990) Second-order optical nonlinearities and photostabilities of 2-N-methylstilbazolium salts. Chemistry of Materials, 2 (6). pp. 685-690. ISSN 0897-4756. https://resolver.caltech.edu/CaltechAUTHORS:20180507-141347911

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Abstract

We have synthesized a number of 2-N-methylstilbazolium salts and measured their powder second harmonic generation (SHG) efficiencies. The pale yellow salt 3'-methoxy-2-N-methylstilbazolium triflate was found to exhibit an SHG efficiency 24 times that of a urea reference standard at 532 nm, and an X-ray diffraction study showed the crystals to be noncentrosymmetric (space group Cc; a = 18.126 (4) Å, b = 7.040 (1) Å, c = 13.315 (2) Å, β = 93.46 (1)°, Z = 4). These crystals are photochemically stable under visible irradiation. On the other hand, 2'-methoxy-2-N-methylstilbazolium triiflate shows no SHG signal; it forms centrosymmetric crystals (space group P2_1/n; a = 11.999 (2) Å, b = 13.458 (2) Å, c = 11.043 (2) A, β = 108.47 (1)°, Z = 4) that undergo photochemical 2 + 2 cycloaddition.


Item Type:Article
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https://dx.doi.org/10.1021/cm00012a017DOIArticle
https://pubs.acs.org/doi/suppl/10.1021/cm00012a017PublisherSupporting Information
Additional Information:© 1990 American Chemical Society. Received April 17, 1990. The research described in this paper was performed by the Jet Propulsion Laboratory, California Institute of Technology, as part of its Center for Space Microelectronics Technology, which is supported by the Strategic Defense Initiative Organization, Innovative Science and Technology Office, through an agreement with the National Aeronautics and Space Administration. S.R.M. thanks Professor Robert Grubbs for access to synthetic facilities at Caltech. The diffractometer used in this study was purchased with a grant from the National Science Foundation (CHE-8219039). We thank Paul Groves and Kelly Perry for technical assistance.
Funders:
Funding AgencyGrant Number
NASA/JPL/CaltechUNSPECIFIED
Strategic Defense Initiative Organization (SDIO)UNSPECIFIED
NSFCHE-8219039
National Research CouncilUNSPECIFIED
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Division of Chemistry and Chemical Engineering8126
Issue or Number:6
Record Number:CaltechAUTHORS:20180507-141347911
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180507-141347911
Official Citation:Second-order optical nonlinearities and photostabilities of 2-N-methylstilbazolium salts Seth R. Marder, Joseph W. Perry, Bruce G. Tiemann, Richard E. Marsh, and William P. Schaefer Chemistry of Materials 1990 2 (6), 685-690 DOI: 10.1021/cm00012a017
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86265
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:07 May 2018 21:38
Last Modified:03 Oct 2019 19:41

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