Grosjean, Daniel and Williams, Edwin L., II and Seinfeld, John H. (1992) Atmospheric oxidation of selected terpenes and related carbonyls: gas-phase carbonyl products. Environmental Science and Technology, 26 (8). pp. 1526-1533. ISSN 0013-936X. doi:10.1021/es00032a005. https://resolver.caltech.edu/CaltechAUTHORS:20180510-152205768
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Abstract
The gas-phase carbonyl products of α-pinene, β-pinene, and d-limonene have been identified and their concentrations measured in experiments involving sunlight irradiations of mixtures of terpene (1-2 ppm) and NO (0.25 ppm) in air. In turn, sunlight irradiations of carbonyl-NO_x mixtures have been carried out for the major high molecular weight carbonyl products of β-pinene (6,6-dimethylbicyclo[3.1.1] heptan-2-one) and d-limonene (4-acetyl-1-methylcyclohexene), and the corresponding carbonyl products have been identified. The nature and yields of these carbonyl products are discussed in terms of oxidation mechanisms involving the OH-terpene, ozone-terpene, OH-carbonyl, and ozone-carbonyl reactions.
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| Additional Information: | © 1992 American Chemical Society. Received for review January 15, 1992. Revised manuscript received April 3, 1992. Accepted April 21, 1992. This work was supported by National Science Foundation Grant ATM-9003186. We thank Eric Grosjean for his assistance in carrying out the experiments and the carbonyl analyses. Ms. Denise Yanez prepared the draft and final versions of the manuscript. | ||||||
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| Issue or Number: | 8 | ||||||
| DOI: | 10.1021/es00032a005 | ||||||
| Record Number: | CaltechAUTHORS:20180510-152205768 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180510-152205768 | ||||||
| Official Citation: | Atmospheric oxidation of selected terpenes and related carbonyls: gas-phase carbonyl products Daniel Grosjean, Edwin L. Williams II, and John H. Seinfeld Environmental Science & Technology 1992 26 (8), 1526-1533 DOI: 10.1021/es00032a005 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 86354 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 14 May 2018 16:38 | ||||||
| Last Modified: | 15 Nov 2021 20:37 |
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