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Physicochemical Characterization of Zeolites SSZ-26 and SSZ-33

Lobo, Raul F. and Pan, Ming and Chan, Ignatius and Medrud, Ronald C. and Zones, Stacey I. and Crozier, Peter A. and Davis, Mark E. (1994) Physicochemical Characterization of Zeolites SSZ-26 and SSZ-33. Journal of Physical Chemistry, 98 (46). pp. 12040-12052. ISSN 0022-3654. https://resolver.caltech.edu/CaltechAUTHORS:20180514-155013871

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Abstract

Detailed characterization of zeolites SSZ-26 and SSZ-33 is presented and includes data from adsorption experiments, X-ray powder diffraction (XRD), electron diffraction (ED), and high-resolution electron microscopy (HREM). Simulated XRD patterns and HREM images of the proposed structures agree very well with all the experimental data. These zeolites are the first synthetic high-silica molecular sieves to contain a three-dimensional pore system comprised of intersecting 10- and 12-ring pores. The structures of SSZ-26 and SSZ-33 are compared to the structures of known zeolites, and the relationships between the geometry of the structure-directing agents used in the synthesis of SSZ-26 and the geometry of the pores are analyzed using energy minimization calculations. Several hypothetical zeolite structures are derived based on the proposed models for SSZ-26 and SSZ-33. SSZ-26 and SSZ-33 are the first examples of molecular sieves whose multidimensional pore systems have been formed by the purposeful design of their structure-directing agents.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/j100097a033DOIArticle
https://pubs.acs.org/doi/suppl/10.1021/j100097a033PublisherSupporting Information
ORCID:
AuthorORCID
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 1994 American Chemical Society. Received: June 4, 1994; In Final Form: August 29, 1994. We are grateful to Chevron Research and Technology Company for financial support. We acknowledge D. E. Cox for assistance in collecting the synchrotron data. The XRD data were collected at X7 A beam line, National Synchrotron Light Source, Brookhaven National Laboratory, which is supported by the U.S. Department of Energy, Division of Material Sciences and Division of Chemical Sciences. We also acknowledge the assistance of G. Zhang and G. Mondo from Chevron Research and Technology Co. in collecting the synchrotron data. M.P. and P.A.C. were supported by the HREM Industrial Associates Program at Arizona State University. HREM work was performed at the Center for HREM at ASU supported by NSF Grant DMR-9115680.
Funders:
Funding AgencyGrant Number
Chevron Research and Technology CompanyUNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
NSFDMR-9115680
Issue or Number:46
Record Number:CaltechAUTHORS:20180514-155013871
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180514-155013871
Official Citation:Physicochemical Characterization of Zeolites SSZ-26 and SSZ-33. Raul F. Lobo, Ming Pan, Ignatius Chan, Ronald C. Medrud, Stacey I. Zones, Peter A. Crozier, and Mark E. Davis. The Journal of Physical Chemistry 1994 98 (46), 12040-12052 DOI: 10.1021/j100097a033
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86399
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 May 2018 16:53
Last Modified:03 Oct 2019 19:43

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