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Synthesis and Properties of a (Diarylamino)ferrocene and Its Radical Cation

Mendiratta, Arjun and Barlow, Stephen and Day, Michael W. and Marder, Seth R. (1999) Synthesis and Properties of a (Diarylamino)ferrocene and Its Radical Cation. Organometallics, 18 (3). pp. 454-456. ISSN 0276-7333. doi:10.1021/om980733g.

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(Di-p-tolylamino)ferrocene (1) was synthesized using Pd-catalyzed C−N bond formation; it is oxidized at −250 mV vs ferrocene in THF. Magnetic susceptibility measurements show the unpaired electron of [1]^+[BF_4]^- (2) to be principally ferrocene-localized; however, the diarylamino moiety leads to a substantial red shift of the ligand-to-metal charge-transfer transition of 2 relative to that of ferrocenium.

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Additional Information:© 1999 American Chemical Society. Received August 31, 1998. Support from the National Science Foundation, Air Force Office of Scientific Research (AFOSR), at Caltech is gratefully acknowledged. The research described in this paper was performed in part by the Jet Propulsion Laboratory (JPL), California Institute of Technology, as part of its Center for Space Microelectronics Technology and was supported by the Ballistic Missile Defense Initiative Organization, Innovative Science and Technology Office, through an agreement with the National Aeronautics and Space Administration (NASA). We also thank Dr. Seth Miller for valuable assistance with the SQUID measurements.
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Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Ballistic Missile Defense OrganizationUNSPECIFIED
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Official Citation:Synthesis and Properties of a (Diarylamino)ferrocene and Its Radical Cation Arjun Mendiratta, Stephen Barlow, Michael W. Day, and Seth R. Marder Organometallics 1999 18 (3), 454-456 DOI: 10.1021/om980733g
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86469
Deposited By: George Porter
Deposited On:21 May 2018 15:36
Last Modified:15 Nov 2021 20:38

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