CaltechAUTHORS
  A Caltech Library Service

Synthesis and Properties of a (Diarylamino)ferrocene and Its Radical Cation

Mendiratta, Arjun and Barlow, Stephen and Day, Michael W. and Marder, Seth R. (1999) Synthesis and Properties of a (Diarylamino)ferrocene and Its Radical Cation. Organometallics, 18 (3). pp. 454-456. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20180518-150646259

[img] PDF (Tables of crystal structure solution and refinement details, atomic coordinates and equivalent isotropic displacement parameters, bond lengths and angles, anisotropic displacement parameters, and hydrogen coordinates and isotropic displacement parameters ) - Supplemental Material
See Usage Policy.

466Kb

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20180518-150646259

Abstract

(Di-p-tolylamino)ferrocene (1) was synthesized using Pd-catalyzed C−N bond formation; it is oxidized at −250 mV vs ferrocene in THF. Magnetic susceptibility measurements show the unpaired electron of [1]^+[BF_4]^- (2) to be principally ferrocene-localized; however, the diarylamino moiety leads to a substantial red shift of the ligand-to-metal charge-transfer transition of 2 relative to that of ferrocenium.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/om980733gDOIArticle
https://pubs.acs.org/doi/suppl/10.1021/om980733gPublisherSupporting Information
Additional Information:© 1999 American Chemical Society. Received August 31, 1998. Support from the National Science Foundation, Air Force Office of Scientific Research (AFOSR), at Caltech is gratefully acknowledged. The research described in this paper was performed in part by the Jet Propulsion Laboratory (JPL), California Institute of Technology, as part of its Center for Space Microelectronics Technology and was supported by the Ballistic Missile Defense Initiative Organization, Innovative Science and Technology Office, through an agreement with the National Aeronautics and Space Administration (NASA). We also thank Dr. Seth Miller for valuable assistance with the SQUID measurements.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
NASA/JPL/CaltechUNSPECIFIED
Ballistic Missile Defense OrganizationUNSPECIFIED
Issue or Number:3
Record Number:CaltechAUTHORS:20180518-150646259
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180518-150646259
Official Citation:Synthesis and Properties of a (Diarylamino)ferrocene and Its Radical Cation Arjun Mendiratta, Stephen Barlow, Michael W. Day, and Seth R. Marder Organometallics 1999 18 (3), 454-456 DOI: 10.1021/om980733g
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86469
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:21 May 2018 15:36
Last Modified:03 Oct 2019 19:44

Repository Staff Only: item control page