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Reaction between Ruthenium(0) Complexes and Dihalo Compounds. A New Method for the Synthesis of Ruthenium Olefin Metathesis Catalysts

Belderrain, Tomàs R. and Grubbs, Robert H. (1997) Reaction between Ruthenium(0) Complexes and Dihalo Compounds. A New Method for the Synthesis of Ruthenium Olefin Metathesis Catalysts. Organometallics, 16 (18). pp. 4001-4003. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20180518-161757126

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Abstract

The synthesis of ruthenium carbenes by the reaction of a Ru(0) compound or Ru(0) precursors with dihalo compounds is reported. A new procedure for the preparation of [Ru(H)_2(H_2)_2(PCy_3)_2] and the use of this complex as a starting material for the synthesis of ruthenium carbenes are presented.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/om970514fDOIArticle
ORCID:
AuthorORCID
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 1997 American Chemical Society. Received June 17, 1997.
Issue or Number:18
Record Number:CaltechAUTHORS:20180518-161757126
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180518-161757126
Official Citation:Reaction between Ruthenium(0) Complexes and Dihalo Compounds. A New Method for the Synthesis of Ruthenium Olefin Metathesis Catalysts Tomás R. Belderrain and Robert H. Grubbs Organometallics 1997 16 (18), 4001-4003 DOI: 10.1021/om970514f
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86479
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:21 May 2018 16:00
Last Modified:03 Oct 2019 19:44

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