Crellin, Kevin C. and Geribaldi, Serge and Beauchamp, J. L. (1994) Site Selective σ-Bond Metathesis Reactions of Sc(CD_3)_2^+ with [2,2-D_2]Propane, [1,1,1,4,4,4-D_6]-n-Butane, and [2-D]Isobutane. Organometallics, 13 (9). pp. 3733-3736. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20180521-125128625
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Abstract
Fourier transform ion cyclotron resonance mass spectrometry is used to show that Sc(CD_3)_2^+ reacts with saturated alkanes larger than ethane in the gas phase by a four center σ-bond metathesis reaction with methane elimination. These processes are facile at room temperature, involve little or no activation energy, and occur preferentially with primary carbon-hydrogen bonds.
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| Alternate Title: | Site Selective .sigma.-Bond Metathesis Reactions of Sc(CD3)2+ with [2,2-D2]Propane, [1,1,1,4,4,4-D6]-n-Butane, and [2-D]Isobutane | ||||||||
| Additional Information: | © 1994 American Chemical Society. Received November 16, 1993. We wish to thank J. K. Perry and Professor W. A. Goddard III for their theoretical work on this system. This work was supported by the National Science Foundation under Grant CHE-9108318, by a grant from Amoco, and by the Office of Naval Research. | ||||||||
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| Issue or Number: | 9 | ||||||||
| Record Number: | CaltechAUTHORS:20180521-125128625 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180521-125128625 | ||||||||
| Official Citation: | Site Selective .sigma.-Bond Metathesis Reactions of Sc(CD3)2+ with [2,2-D2]Propane, [1,1,1,4,4,4-D6]-n-Butane, and [2-D]Isobutane Kevin C. Crellin, Serge Geribaldi, and J. L. Beauchamp Organometallics 1994 13 (9), 3733-3736 DOI: 10.1021/om00021a054 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 86502 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | George Porter | ||||||||
| Deposited On: | 21 May 2018 20:12 | ||||||||
| Last Modified: | 03 Oct 2019 19:44 |
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