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Site Selective σ-Bond Metathesis Reactions of Sc(CD_3)_2^+ with [2,2-D_2]Propane, [1,1,1,4,4,4-D_6]-n-Butane, and [2-D]Isobutane

Crellin, Kevin C. and Geribaldi, Serge and Beauchamp, J. L. (1994) Site Selective σ-Bond Metathesis Reactions of Sc(CD_3)_2^+ with [2,2-D_2]Propane, [1,1,1,4,4,4-D_6]-n-Butane, and [2-D]Isobutane. Organometallics, 13 (9). pp. 3733-3736. ISSN 0276-7333. https://resolver.caltech.edu/CaltechAUTHORS:20180521-125128625

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Abstract

Fourier transform ion cyclotron resonance mass spectrometry is used to show that Sc(CD_3)_2^+ reacts with saturated alkanes larger than ethane in the gas phase by a four center σ-bond metathesis reaction with methane elimination. These processes are facile at room temperature, involve little or no activation energy, and occur preferentially with primary carbon-hydrogen bonds.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/om00021a054DOIArticle
ORCID:
AuthorORCID
Beauchamp, J. L.0000-0001-8839-4822
Alternate Title:Site Selective .sigma.-Bond Metathesis Reactions of Sc(CD3)2+ with [2,2-D2]Propane, [1,1,1,4,4,4-D6]-n-Butane, and [2-D]Isobutane
Additional Information: © 1994 American Chemical Society. Received November 16, 1993. We wish to thank J. K. Perry and Professor W. A. Goddard III for their theoretical work on this system. This work was supported by the National Science Foundation under Grant CHE-9108318, by a grant from Amoco, and by the Office of Naval Research.
Funders:
Funding AgencyGrant Number
NSFCHE-9108318
AmocoUNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics8895
Issue or Number:9
Record Number:CaltechAUTHORS:20180521-125128625
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180521-125128625
Official Citation:Site Selective .sigma.-Bond Metathesis Reactions of Sc(CD3)2+ with [2,2-D2]Propane, [1,1,1,4,4,4-D6]-n-Butane, and [2-D]Isobutane Kevin C. Crellin, Serge Geribaldi, and J. L. Beauchamp Organometallics 1994 13 (9), 3733-3736 DOI: 10.1021/om00021a054
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86502
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:21 May 2018 20:12
Last Modified:03 Oct 2019 19:44

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