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(Bipyridyl-N,N')diiodoplatinum(II)

Connick, William B. and Gray, Harry B. (1994) (Bipyridyl-N,N')diiodoplatinum(II). Acta Crystallographica Section C, C50 (7). pp. 1040-1042. ISSN 0108-2701. https://resolver.caltech.edu/CaltechAUTHORS:20180524-150509080

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Abstract

Square-planar (bipyridyl-N,N')diiodoplatinum(II), [PtI_2(C_(10)H_8N_2)], has normal Pt--N(bipyridyl) [2.029 (7) Å] and Pt--I bonds [2.589 (2) Å]. The bipyridyl ligand exhibits normal distances and angles. Because of steric effects, the intramolecular I...I separation [3.587 (1) Å] and the corresponding I--Pt--I angle [87.7 (1)°] are significantly smaller than those observed for other cis-bis(iodo)bis(N-donor) complexes. The parallel square-planar units stack to form a chain structure. Relative lateral displacement of consecutive molecules along a chain results in a Pt..-Pt distance [5.291 (1) Å] considerably longer than the interplanar spacing [3.510 (11) Å].


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1107/S0108270193012648DOIArticle
ORCID:
AuthorORCID
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 1994 International Union of Crystallography. (Received 20 July 1993; accepted 11 November 1993) We thank L. M. Henling, R. E. Marsh, V. M. Miskowski and W. P. Schaefer for expert assistance and helpful discussions. This work was supported by the National Science Foundation and the Office of Naval Research.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Division of Chemistry and Chemical Engineering8826
Issue or Number:7
Record Number:CaltechAUTHORS:20180524-150509080
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180524-150509080
Official Citation:Connick, W. B. & Gray, H. B. (1994). Acta Cryst. C50, 1040-1042.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86595
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:24 May 2018 22:28
Last Modified:22 Nov 2019 09:58

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