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Manganese Microperoxidase-8

Low, Donald W. and Abedin, Sakena and Yang, Grace and Winkler, Jay R. and Gray, Harry B. (1998) Manganese Microperoxidase-8. Inorganic Chemistry, 37 (8). pp. 1841-1843. ISSN 0020-1669. http://resolver.caltech.edu/CaltechAUTHORS:20180525-140834681

[img] PDF (The metal-free MP8 absorption spectrum; a chromatographic trace of Mn(III)MP8; mass spectra of metal-free MP8 and Mn(III)MP8; and the resonance Raman spectrum of Mn(III)MP8 (4 pages)) - Supplemental Material
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Abstract

Demetalation of Fe(III) microperoxidase-8 (MP8) by anhydrous HF gives metal-free MP8, a convenient starting material for a wide variety of metal-substituted MP8 derivatives, including Mn(III)MP8. Mn(III)MP8 was produced by treatment of metal-free MP8 with manganous acetate in aerated aqueous solution; it was characterized by mass spectrometry and UV−visible absorption spectroscopy. Resonance Raman spectra suggest that Mn(III)MP8 contains histidine and water axial ligands at neutral pH. The Mn(IV)=O derivative is readily prepared by oxidation of Mn(III)MP8 with hydrogen peroxide or Ru(bpy)_3^(3+) (bpy = 2,2‘-bipyridine).


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/ic971166cDOIArticle
https://pubs.acs.org/doi/suppl/10.1021/ic971166cPublisherSupporting Information
ORCID:
AuthorORCID
Winkler, Jay R.0000-0002-4453-9716
Additional Information:© 1998 American Chemical Society. ReceiVed September 13, 1997. We thank Jane Saunders, Gary Hathaway, and Peter Green for assistance with mass spectrometry. S.A. was a participant in the Caltech SURF program. D.W.L. acknowledges a fellowship from the Parsons Foundation. This work was supported by the NSF.
Funders:
Funding AgencyGrant Number
Caltech Summer Undergraduate Research Fellowship (SURF)UNSPECIFIED
Ralph M. Parsons FoundationUNSPECIFIED
NSFUNSPECIFIED
Record Number:CaltechAUTHORS:20180525-140834681
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20180525-140834681
Official Citation:Manganese Microperoxidase-8 Donald W. Low, Sakena Abedin, Grace Yang, Jay R. Winkler, and Harry B. Gray Inorganic Chemistry 1998 37 (8), 1841-1843 DOI: 10.1021/ic971166c
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86640
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:29 May 2018 15:53
Last Modified:29 May 2018 15:53

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