Chang, Christopher J. and Low, Donald W. and Gray, Harry B. (1997) Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes. Inorganic Chemistry, 36 (3). pp. 270-271. ISSN 0020-1669. doi:10.1021/ic961023a. https://resolver.caltech.edu/CaltechAUTHORS:20180529-113212317
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Abstract
Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear μ-nitrido-activated complex accounts satisfactorily for the observed kinetics data.
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| Additional Information: | © 1997 American Chemical Society. Received August 22, 1996. We thank John Bercaw, Justin DuBois, and Jay Winkler for helpful discussions and Fred Anson for the loan of a thermostatable cell holder. C.J.C. participated in the Summer Undergraduate Research Fellowship (SURF) program at Caltech during 1995 and 1996. D.W.L. acknowledges a fellowship from the Parsons Foundation. This work was supported by the NSF. | ||||||||
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| Issue or Number: | 3 | ||||||||
| DOI: | 10.1021/ic961023a | ||||||||
| Record Number: | CaltechAUTHORS:20180529-113212317 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180529-113212317 | ||||||||
| Official Citation: | Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes Christopher J. Chang, Donald W. Low, and Harry B. Gray Inorganic Chemistry 1997 36 (3), 270-271 DOI: 10.1021/ic961023a | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 86666 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | George Porter | ||||||||
| Deposited On: | 29 May 2018 19:43 | ||||||||
| Last Modified: | 15 Nov 2021 20:40 |
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