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Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes

Chang, Christopher J. and Low, Donald W. and Gray, Harry B. (1997) Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes. Inorganic Chemistry, 36 (3). pp. 270-271. ISSN 0020-1669. https://resolver.caltech.edu/CaltechAUTHORS:20180529-113212317

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Abstract

Nitrogen atom transfer from salen-derived nitridomanganese(V) to manganese(III) Schiff-base complexes occurs under aerobic conditions in solution at room temperature. A mechanism involving chloride dissociation followed by the formation and decay of a binuclear μ-nitrido-activated complex accounts satisfactorily for the observed kinetics data.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/ic961023aDOIArticle
ORCID:
AuthorORCID
Gray, Harry B.0000-0002-7937-7876
Additional Information:© 1997 American Chemical Society. Received August 22, 1996. We thank John Bercaw, Justin DuBois, and Jay Winkler for helpful discussions and Fred Anson for the loan of a thermostatable cell holder. C.J.C. participated in the Summer Undergraduate Research Fellowship (SURF) program at Caltech during 1995 and 1996. D.W.L. acknowledges a fellowship from the Parsons Foundation. This work was supported by the NSF.
Funders:
Funding AgencyGrant Number
Caltech Summer Undergraduate Research Fellowship (SURF)UNSPECIFIED
Ralph M. Parsons FoundationUNSPECIFIED
NSFUNSPECIFIED
Issue or Number:3
Record Number:CaltechAUTHORS:20180529-113212317
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180529-113212317
Official Citation:Reversible Nitrogen Atom Transfer between Nitridomanganese(V) and Manganese(III) Schiff-Base Complexes Christopher J. Chang, Donald W. Low, and Harry B. Gray Inorganic Chemistry 1997 36 (3), 270-271 DOI: 10.1021/ic961023a
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86666
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:29 May 2018 19:43
Last Modified:22 Nov 2019 09:58

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