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Component Dynamics Miscible Polymer Blends: A Two-Dimensional Deuteron NMR Investigation

Chung, G.-C. and Kornfield, J. A. and Smith, S. D. (1994) Component Dynamics Miscible Polymer Blends: A Two-Dimensional Deuteron NMR Investigation. Macromolecules, 27 (4). pp. 964-973. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20180529-144753548

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Abstract

The dynamics of individual components in 1,4-polyisoprene/poly(vinylethylene) miscible blends are studied using two-dimensional deuteron exchange NMR. The rate of the backbone reorientation process near the glass transition is quantitatively determined for each species in a miscible blend as a function of temperature. We demonstrate that the broad glass transition arises both from a wide distribution of segmental motional rates for each species and from intrinsic differences in the motional rate between the two species. In addition, the temperature dependence of their motional rates in the blend DSC glass transition region suggests that the two components undergo distinct effective glass transitions, which is consistent with previously observed thermorheologically complex behavior. The origins of dynamic heterogeneity are examined further by comparing the experimental results with a simple model calculation that takes into account the effect of composition variations in an ideal miscible blend. This comparison suggests that the observed dynamic heterogeneities can be explained only by including two distinct contributions: local composition variations in the blend and intrinsic differences in chain mobilities.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/ma00082a013DOIArticle
ORCID:
AuthorORCID
Kornfield, J. A.0000-0001-6746-8634
Additional Information:© 1994 American Chemical Society. Received August 9, 1993; Revised Manuscript Received November 22, 1993. We gratefully acknowledge the support of the National Science Foundation Presidential Young Investigator Award (J.A.K.), Chevron, and the Caltech Consortium in Chemistry and Chemical Engineering: E. I. du Pont de Nemours and Co., Inc., and Eastman Kodak Co.
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Funding AgencyGrant Number
NSFUNSPECIFIED
Chevron CorporationUNSPECIFIED
Caltech Consortium in Chemistry and Chemical EngineeringUNSPECIFIED
Issue or Number:4
Record Number:CaltechAUTHORS:20180529-144753548
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180529-144753548
Official Citation:Component Dynamics Miscible Polymer Blends: A Two-Dimensional Deuteron NMR Investigation G. C. Chung, J. A. Kornfield, and S. D. Smith Macromolecules 1994 27 (4), 964-973 DOI: 10.1021/ma00082a013
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86680
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:29 May 2018 22:37
Last Modified:03 Oct 2019 19:46

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