Fujimura, Osamu and Fu, Gregory C. and Grubbs, Robert H. (1994) The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis. Journal of Organic Chemistry, 59 (15). pp. 4029-4031. ISSN 0022-3263. doi:10.1021/jo00094a002. https://resolver.caltech.edu/CaltechAUTHORS:20180530-141851654
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Abstract
An efficient method for the construction of five- and six-membered cyclic vinyl ethers from unsaturated esters using stoichiometric titanium reagents to convert the esters to acyclic olefinic enol ethers which are then transformed to the desired products by catalytic ring-closing olefin metathesis with a molybdenum alkylidene complex is described.
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| Additional Information: | © 1994 American Chemical Society. Received January 21, 1994 (Revised Manuscript Received May 23, 1994) Support has been provided by the National Institutes of Health. Fellowship support for O.F. by the Ube Industries, Ltd., is gratefully acknowledged. O.F. thanks Dr. Z. Wu for helpful discussions. | |||||||||
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| Issue or Number: | 15 | |||||||||
| DOI: | 10.1021/jo00094a002 | |||||||||
| Record Number: | CaltechAUTHORS:20180530-141851654 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180530-141851654 | |||||||||
| Official Citation: | The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis Osamu Fujimura, Gregory C. Fu, and Robert H. Grubbs The Journal of Organic Chemistry 1994 59 (15), 4029-4031 DOI: 10.1021/jo00094a002 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 86724 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 01 Jun 2018 21:56 | |||||||||
| Last Modified: | 15 Nov 2021 20:41 |
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