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The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis

Fujimura, Osamu and Fu, Gregory C. and Grubbs, Robert H. (1994) The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis. Journal of Organic Chemistry, 59 (15). pp. 4029-4031. ISSN 0022-3263. https://resolver.caltech.edu/CaltechAUTHORS:20180530-141851654

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Abstract

An efficient method for the construction of five- and six-membered cyclic vinyl ethers from unsaturated esters using stoichiometric titanium reagents to convert the esters to acyclic olefinic enol ethers which are then transformed to the desired products by catalytic ring-closing olefin metathesis with a molybdenum alkylidene complex is described.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/jo00094a002DOIArticle
https://pubs.acs.org/doi/suppl/10.1021/jo00094a002PublisherSupporting Information
ORCID:
AuthorORCID
Fu, Gregory C.0000-0002-0927-680X
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 1994 American Chemical Society. Received January 21, 1994 (Revised Manuscript Received May 23, 1994) Support has been provided by the National Institutes of Health. Fellowship support for O.F. by the Ube Industries, Ltd., is gratefully acknowledged. O.F. thanks Dr. Z. Wu for helpful discussions.
Funders:
Funding AgencyGrant Number
NIHUNSPECIFIED
Ube Industries, Ltd.UNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arnold and Mabel Beckman Laboratories of Chemical Synthesis8961
Issue or Number:15
Record Number:CaltechAUTHORS:20180530-141851654
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180530-141851654
Official Citation:The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis Osamu Fujimura, Gregory C. Fu, and Robert H. Grubbs The Journal of Organic Chemistry 1994 59 (15), 4029-4031 DOI: 10.1021/jo00094a002
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86724
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:01 Jun 2018 21:56
Last Modified:03 Oct 2019 19:47

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