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Pushing the Limits for Thiol−Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day

Antoni, Per and Robb, Maxwell J. and Campos, Luis and Montanez, Maria and Hult, Anders and Malström, Eva and Malkoch, Michael and Hawker, Craig J. (2010) Pushing the Limits for Thiol−Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day. Macromolecules, 43 (16). pp. 6625-6631. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20180605-164810729

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Abstract

Dendrimer synthesis should not be tedious and time-consuming. By utilizing an AB2−CD2 approach and having orthogonal, “clickable” groups on each monomer, the time for dendrimer assembly can be drastically reduced. This was shown by preparation of a sixth generation dendrimer from starting monomer units in a single day.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/ma101242uDOIArticle
https://pubs.acs.org/doi/suppl/10.1021/ma101242uPublisherSupporting Information
ORCID:
AuthorORCID
Robb, Maxwell J.0000-0002-0528-9857
Additional Information:© 2010 American Chemical Society. Received June 3, 2010; Revised Manuscript Received July 7, 2010. Financial support from the NSF (CHE-0957492, the MRSEC Program DMR-0520415 (MRL-UCSB)), UC Regents for a President’s Fellowship (L.M.C.) and Graduate Fellowship (M.J.R.), the Swedish Research Council (M.M.) (Grant 2006-3617), Bengt Lundqvists Minnesfond (P.A.), and Instituto de Salud Carlos III (M.I.M.) is greatly acknowledged.
Funders:
Funding AgencyGrant Number
NSFCHE-0957492
NSFDMR-0520415
UC RegentsUNSPECIFIED
Swedish Research Council2006-3617
Bengt Lundqvists MinnesfondUNSPECIFIED
Instituto de Salud Carlos IIIUNSPECIFIED
Issue or Number:16
Record Number:CaltechAUTHORS:20180605-164810729
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180605-164810729
Official Citation:Pushing the Limits for Thiol−Ene and CuAAC Reactions: Synthesis of a 6th Generation Dendrimer in a Single Day Per Antoni, Maxwell J. Robb, Luis Campos, Maria Montanez, Anders Hult, Eva Malmström, Michael Malkoch, and Craig J. Hawker Macromolecules 2010 43 (16), 6625-6631 DOI: 10.1021/ma101242u
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:86818
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:06 Jun 2018 14:54
Last Modified:03 Oct 2019 19:48

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