Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion

Drover, Marcus W. and Nagata, Koichi and Peters, Jonas C. (2018) Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion. Chemical Communications, 54 (57). pp. 7916-7919. ISSN 1359-7345. PMCID PMC6095131. doi:10.1039/c8cc04321c. https://resolver.caltech.edu/CaltechAUTHORS:20180628-102927648

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Abstract

In a fusion of two ubiquitous organometallic reagents, triphenylphosphine (PPh_3) and tetraphenylborate (BPh_4−), the 9-phosphatriptycene-10-phenylborate (PTB) anion has been prepared for the first time. This borato species has been fully characterized by a suite of spectroscopic methods, and initial reactivity studies introduce it as a competent ligand for transition metals, including Co(II) and Fe(II).

Item Type:

Article

Related URLs:

URL	URL Type	Description
https://doi.org/10.1039/c8cc04321c	DOI	Article
http://www.rsc.org/suppdata/c8/cc/c8cc04321c/c8cc04321c1.pdf	Publisher	Supplementary Information
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6095131	PubMed Central	Article

ORCID:

Author	ORCID
Drover, Marcus W.	0000-0002-2186-1040
Nagata, Koichi	0000-0003-3767-9507
Peters, Jonas C.	0000-0002-6610-4414

Additional Information:

© 2018 The Royal Society of Chemistry. Received 30th May 2018, Accepted 22nd June 2018. First published on 22nd June 2018. This work was supported by the NIH (GM070757), NSERC (Banting PDF award to MWD), and the Resnick Sustainability Institute at Caltech (Postdoctoral award to MWD). KN thanks the Japan Society for the Promotion of Science (JSPS) for an overseas postdoctoral fellowship. We thank Larry Henling and Dr Mike Takase for assistance with X-ray crystallography.

Group:

Resnick Sustainability Institute

Funders:

Funding Agency	Grant Number
NIH	GM070757
Natural Sciences and Engineering Research Council of Canada (NSERC)	UNSPECIFIED
Resnick Sustainability Institute	UNSPECIFIED
Japan Society for the Promotion of Science (JSPS)	UNSPECIFIED

Issue or Number:

PubMed Central ID:

PMC6095131

DOI:

10.1039/c8cc04321c

Record Number:

CaltechAUTHORS:20180628-102927648

Persistent URL:

https://resolver.caltech.edu/CaltechAUTHORS:20180628-102927648

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No commercial reproduction, distribution, display or performance rights in this work are provided.

ID Code:

87437

Collection:

CaltechAUTHORS

Deposited By:

Tony Diaz

Deposited On:

28 Jun 2018 17:43

Last Modified:

09 Mar 2022 18:48

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