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Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion

Drover, Marcus W. and Nagata, Koichi and Peters, Jonas C. (2018) Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion. Chemical Communications, 54 (57). pp. 7916-7919. ISSN 1359-7345. https://resolver.caltech.edu/CaltechAUTHORS:20180628-102927648

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Abstract

In a fusion of two ubiquitous organometallic reagents, triphenylphosphine (PPh_3) and tetraphenylborate (BPh_4−), the 9-phosphatriptycene-10-phenylborate (PTB) anion has been prepared for the first time. This borato species has been fully characterized by a suite of spectroscopic methods, and initial reactivity studies introduce it as a competent ligand for transition metals, including Co(II) and Fe(II).


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1039/c8cc04321cDOIArticle
http://www.rsc.org/suppdata/c8/cc/c8cc04321c/c8cc04321c1.pdfPublisherSupplementary Information
ORCID:
AuthorORCID
Drover, Marcus W.0000-0002-2186-1040
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2018 The Royal Society of Chemistry. Received 30th May 2018, Accepted 22nd June 2018. First published on 22nd June 2018. This work was supported by the NIH (GM070757), NSERC (Banting PDF award to MWD), and the Resnick Sustainability Institute at Caltech (Postdoctoral award to MWD). KN thanks the Japan Society for the Promotion of Science (JSPS) for an overseas postdoctoral fellowship. We thank Larry Henling and Dr Mike Takase for assistance with X-ray crystallography.
Group:Resnick Sustainability Institute
Funders:
Funding AgencyGrant Number
NIHGM070757
Natural Sciences and Engineering Research Council of Canada (NSERC)UNSPECIFIED
Resnick Sustainability InstituteUNSPECIFIED
Japan Society for the Promotion of Science (JSPS)UNSPECIFIED
Issue or Number:57
Record Number:CaltechAUTHORS:20180628-102927648
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180628-102927648
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:87437
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:28 Jun 2018 17:43
Last Modified:03 Oct 2019 19:56

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