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In situ analysis of opal in Gale crater, Mars

Rapin, W. and Chauviré, B. and Gabriel, T. S. J. and McAdam, A. C. and Ehlmann, B. L. and Hardgrove, C. and Meslin, P.-Y. and Rondeau, B. and Dehouck, E. and Franz, H. B. and Mangold, N. and Chipera, S. J. and Wiens, R. C. and Frydenvang, J. and Schröder, S. (2018) In situ analysis of opal in Gale crater, Mars. Journal of Geophysical Research. Planets, 123 (8). pp. 1955-1972. ISSN 2169-9097. https://resolver.caltech.edu/CaltechAUTHORS:20180705-070817027

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Abstract

Silica enrichments resulting in up to ~90 wt% SiO_2 have been observed by the Curiosity rover's instruments in Gale crater, Mars, within the Murray and Stimson formations. Samples acquired by the rover drill revealed a significant abundance of an X‐ray amorphous silica phase. Laser‐induced breakdown spectroscopy (LIBS) highlights an overall correlation of the hydrogen signal with silica content for these Si‐enriched targets. The increased hydration of the high‐silica rocks compared to the surrounding bedrock is also confirmed by active neutron spectroscopy. Laboratory LIBS experiments have been performed to calibrate the hydrogen signal and show that the correlation observed on Mars is consistent with a silica phase containing on average 6.3 ± 1.4 wt% water. X‐ray diffraction and LIBS measurements indicate that opal‐A, amorphous hydrated silica, is the most likely phase containing this water in the rocks. Pyrolysis experiments were also performed on drilled samples by the Sample Analysis at Mars (SAM) instrument to measure volatile content, but the data suggests that most of the water was released during handling prior to pyrolysis. The inferred low‐temperature release of water helps constrain the nature of the opal. Given the geological context and the spatial association with other phases such as calcium sulfates, the opal was likely formed from multiple diagenetic fluid events and possibly represents the latest significant water‐rock interaction in these sedimentary rocks.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1029/2017JE005483DOIArticle
ORCID:
AuthorORCID
Rapin, W.0000-0003-4660-8006
Chauviré, B.0000-0003-0431-6312
Gabriel, T. S. J.0000-0002-9767-4153
Ehlmann, B. L.0000-0002-2745-3240
Hardgrove, C.0000-0002-8556-6630
Meslin, P.-Y.0000-0002-0703-3951
Dehouck, E.0000-0002-1368-4494
Mangold, N.0000-0002-0022-0631
Wiens, R. C.0000-0002-3409-7344
Frydenvang, J.0000-0001-9294-1227
Schröder, S.0000-0003-1870-3663
Additional Information:© 2018 The Authors. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. Received 9 NOV 2017; Accepted 12 JUN 2018; Accepted article online 3 JUL 2018; Published online 4 AUG 2018. The research was funded at Caltech by the Division of Geological and Planetary Sciences Postdoctoral Fellowship and supported by a NASA MSL Participating Scientist Program grant to B. L. Ehlmann. The work performed at Université Paul Sabatier was part of a PhD thesis (Rapin, 2016), and laboratory LIBS experiments were conducted at Institut de Recherche en Astrophysique et Planétologie (IRAP) with support from CNES. MSL/ChemCam U.S. operations were funded by the NASA Mars Exploration Program. Funding for ChemCam operations in France was provided by CNES. The authors gratefully acknowledge the support of all of the people at NASA‐JPL involved in making MSL a successful mission. We also thank two anonymous reviewers for their helpful comments. We acknowledge the Agence Nationale de la Recherche (ANR) under the program ANR‐16‐CE31‐0012 entitled “Mars‐Prime” for helping collaborative efforts in this study. The authors thankfully recognize the help of Paul Thomas, from the University of Technology, Sydney, for TGA on opals. A. C. M. thanks NASA's MSL Participating Scientist program for supporting this effort. All data collected on Mars by MSL/Curiosity used in this study are available on the PDS (Planetary Data System) at pds.nasa.gov. Data shown in Figures 1 and 2 are accessible in the supporting information.
Group:Astronomy Department
Funders:
Funding AgencyGrant Number
CaltechUNSPECIFIED
NASAUNSPECIFIED
Centre National d'Études Spatiales (CNES)UNSPECIFIED
Agence Nationale pour la Recherche (ANR)ANR-16-CE31-0012
Subject Keywords:opal; Mars; MSL; Gale crater; hydrogen; water
Issue or Number:8
Record Number:CaltechAUTHORS:20180705-070817027
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180705-070817027
Official Citation:Rapin, W., Chauviré, B., Gabriel, T. S. J., McAdam, A. C., Ehlmann, B. L., Hardgrove, C., et al. (2018). In situ analysis of opal in Gale crater, Mars. Journal of Geophysical Research: Planets, 123, 1955–1972. https://doi.org/10.1029/2017JE005483
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:87542
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:05 Jul 2018 17:28
Last Modified:20 Apr 2020 08:47

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