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Preparation of hydroxytelechelic poly(butadiene) via ring-opening metathesis polymerization employing a well-defined metathesis catalyst

Hillmyer, Marc A. and Grubbs, Robert H. (1993) Preparation of hydroxytelechelic poly(butadiene) via ring-opening metathesis polymerization employing a well-defined metathesis catalyst. Macromolecules, 26 (4). pp. 872-874. ISSN 0024-9297. https://resolver.caltech.edu/CaltechAUTHORS:20180720-123814160

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Abstract

In this paper we show that ring-opening metathesis polymerization (ROMP) using a discrete metal alkylidene catalyst offers another alternative polymerization technique that is applicable to the synthesis of well-defined HTPBD.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://dx.doi.org/10.1021/ma00056a051DOIArticle
ORCID:
AuthorORCID
Hillmyer, Marc A.0000-0001-8255-3853
Grubbs, Robert H.0000-0002-0057-7817
Additional Information:© 1993 American Chemical Society. Received September 9, 1992. Revised Manuscript Received November 9, 1992. This work was supported by the National Science Foundation, the Thiokol Corporation, and the Caltech Chemical Consortium (Du Pont, Kodak, Shell, and 3M). We thank Dr. Lou F. Cannizzo for helpful discussions and Dr. Lynda K. Johnson for providing the sample of catalyst 1 that was used in this work.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Thiokol Chemical CorporationUNSPECIFIED
Caltech Consortium in Chemistry and Chemical EngineeringUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arnold and Mabel Beckman Laboratories of Chemical Synthesis8721
Issue or Number:4
Record Number:CaltechAUTHORS:20180720-123814160
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180720-123814160
Official Citation:Preparation of hydroxytelechelic poly(butadiene) via ring-opening metathesis polymerization employing a well-defined metathesis catalyst Marc A. Hillmyer and Robert H. Grubbs Macromolecules 1993 26 (4), 872-874 DOI: 10.1021/ma00056a051
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88063
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:23 Jul 2018 21:11
Last Modified:03 Oct 2019 20:02

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