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Electron impact ionization of phenylsilane. Evidence for the formation of phenylsilyl and silacycloheptatrienyl cations

Murthy, Srihari and Nagano, Yatsuhisa and Beauchamp, J. L. (1992) Electron impact ionization of phenylsilane. Evidence for the formation of phenylsilyl and silacycloheptatrienyl cations. Journal of the American Chemical Society, 114 (9). pp. 3573-3574. ISSN 0002-7863. doi:10.1021/ja00035a072. https://resolver.caltech.edu/CaltechAUTHORS:20180724-152025456

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Abstract

Since the original suggestion by Mayerson and co-workers that hydrogen atom loss from the molecular toluene cation results in the formation of the cycloheptatrienyl cation (Ia), a number of studies have attempted to elucidate the structure, energetics, and modes of formation of C_7H_7^+ isomers. It is now well understood that electron impact ionization of toluene yields both Ia and IIa. The relative yield of the two isomers is dependent on the internal energy content of the molecular toluene cation.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja00035a072DOIArticle
ORCID:
AuthorORCID
Beauchamp, J. L.0000-0001-8839-4822
Additional Information:© 1992 American Chemical Society. Received December 31, 1991. This work was supported by Grant CHE-91-08318 from the National Science Foundation. One of the authors (Y.N.) gratefully acknowledges financial support from the Yamada Science Foundation of Japan for a visiting associateship at the California Institute of Technology.
Funders:
Funding AgencyGrant Number
NSFCHE-91-08318
Yamada Science FoundationUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Arthur Amos Noyes Laboratory of Chemical Physics8553
Issue or Number:9
DOI:10.1021/ja00035a072
Record Number:CaltechAUTHORS:20180724-152025456
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180724-152025456
Official Citation:Electron impact ionization of phenylsilane. Evidence for the formation of phenylsilyl and silacycloheptatrienyl cations Srihari Murthy, Yatsuhisa Nagano, and J. L. Beauchamp Journal of the American Chemical Society 1992 114 (9), 3573-3574 DOI: 10.1021/ja00035a072
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88215
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:25 Jul 2018 16:54
Last Modified:16 Nov 2021 00:24

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