Murthy, Srihari and Nagano, Yatsuhisa and Beauchamp, J. L. (1992) Electron impact ionization of phenylsilane. Evidence for the formation of phenylsilyl and silacycloheptatrienyl cations. Journal of the American Chemical Society, 114 (9). pp. 3573-3574. ISSN 0002-7863. doi:10.1021/ja00035a072. https://resolver.caltech.edu/CaltechAUTHORS:20180724-152025456
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Abstract
Since the original suggestion by Mayerson and co-workers that hydrogen atom loss from the molecular toluene cation results in the formation of the cycloheptatrienyl cation (Ia), a number of studies have attempted to elucidate the structure, energetics, and modes of formation of C_7H_7^+ isomers. It is now well understood that electron impact ionization of toluene yields both Ia and IIa. The relative yield of the two isomers is dependent on the internal energy content of the molecular toluene cation.
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| Additional Information: | © 1992 American Chemical Society. Received December 31, 1991. This work was supported by Grant CHE-91-08318 from the National Science Foundation. One of the authors (Y.N.) gratefully acknowledges financial support from the Yamada Science Foundation of Japan for a visiting associateship at the California Institute of Technology. | ||||||
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| Issue or Number: | 9 | ||||||
| DOI: | 10.1021/ja00035a072 | ||||||
| Record Number: | CaltechAUTHORS:20180724-152025456 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180724-152025456 | ||||||
| Official Citation: | Electron impact ionization of phenylsilane. Evidence for the formation of phenylsilyl and silacycloheptatrienyl cations Srihari Murthy, Yatsuhisa Nagano, and J. L. Beauchamp Journal of the American Chemical Society 1992 114 (9), 3573-3574 DOI: 10.1021/ja00035a072 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 88215 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 25 Jul 2018 16:54 | ||||||
| Last Modified: | 16 Nov 2021 00:24 |
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