Newman, Roger and Badger, Richard M. (1952) Infrared Spectra of Cyanuric Acid and Deutero Cyanuric Acid. Journal of the American Chemical Society, 74 (14). pp. 3545-3548. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20180725-111210108
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Abstract
The infrared spectra of sublimed films of cyanuric acid and deutero cyanuric acid, and the polarized spectra of (101) single crystals of cyanuric acid are reported. The active valence fundamentals and the higher frequency bending vibrations have been identified. A characteristic feature of the spectrum is the occurrence of several doublet bands which represent pairs of vibrations whose degeneracy is removed in the potential field of the crystal. The splitting of the carbonyl frequency is very small which is taken to indicate the near equivalence of all C=O bonds in the molecule. The splitting of N-H valence vibrations is large indicating the presence of two considerably different hydrogen bonds. These results are in disagreement with the X-ray structure determination of Wiebenga and Moerman, which is believed to be in some error.
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| Additional Information: | © 1952 American Chemical Society. Received February 25, 1952. This research was supported by the Office of Naval Research under Contract N6-ori-102, VI. We are indebted to Dr. R. A. Pasternak for the X-ray measurements made in connection with the verification of the orientation of the cyanuric acid crystals. | ||||||
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| Issue or Number: | 14 | ||||||
| Record Number: | CaltechAUTHORS:20180725-111210108 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180725-111210108 | ||||||
| Official Citation: | Infrared Spectra of Cyanuric Acid and Deutero Cyanuric Acid1 Roger Newman and Richard M. Badger Journal of the American Chemical Society 1952 74 (14), 3545-3548 DOI: 10.1021/ja01134a026 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 88252 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 25 Jul 2018 20:41 | ||||||
| Last Modified: | 03 Oct 2019 20:04 |
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