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The Frequency of the Third Harmonic O—H Band of Methanol in Various Solvents, and the Hydrogen Bonding of Methanol with Aromatic Hydrocarbons

Jones, Llewellyn H. and Badger, Richard M. (1951) The Frequency of the Third Harmonic O—H Band of Methanol in Various Solvents, and the Hydrogen Bonding of Methanol with Aromatic Hydrocarbons. Journal of the American Chemical Society, 73 (7). pp. 3132-3134. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20180725-111210728

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Abstract

The absorption spectra of dilute solutions of methanol in several solvents have been observed in the region of the third harmonic of the OH band. In non-polar solvents the OH frequency is shifted from its position in the vapor by an amount proportional to (D - 1)/(2D + 1) where D is the static dielectric constant of the medium. In certain polar chlorinated solvents the frequency shift is less, but in aromatic solvents the large shift is taken as an indication of hydrogen bond formation.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja01151a039DOIArticle
Additional Information:© 1951 American Chemical Society. Received December 20, 1950.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Gates and Crellin Laboratories of Chemistry1504
Issue or Number:7
Record Number:CaltechAUTHORS:20180725-111210728
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180725-111210728
Official Citation:The Frequency of the Third Harmonic O—H Band of Methanol in Various Solvents, and the Hydrogen Bonding of Methanol with Aromatic Hydrocarbons Llewellyn H. Jones and Richard M. Badger Journal of the American Chemical Society 1951 73 (7), 3132-3134 DOI: 10.1021/ja01151a039
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88259
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:25 Jul 2018 20:59
Last Modified:03 Oct 2019 20:04

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