Goldish, Elihu and Hedberg, Kenneth and Marsh, Richard E. and Schomaker, Verner (1955) An Electron Diffraction Investigation of Dimethyl Selenide. Journal of the American Chemical Society, 77 (11). pp. 2948-2949. ISSN 0002-7863. doi:10.1021/ja01616a005. https://resolver.caltech.edu/CaltechAUTHORS:20180725-111211759
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20180725-111211759
Abstract
The results of an electron diffraction investigation of (CH_3)_2Se arc C-H/Se-C, 1.09/1.97 ( assumed); Se-C, 1.977 ± 0.012 Å.; Se•••H, 2.571 ± 0.034 Å.; C•••C, 2.98 ± 0.23 Å.; ∠C-Se-C, 98 ± 10°; and ∠Se-C-H, 110.5 ± 3.5°. The selenium-carbon distance of 1.98 Å. leads to a single-bond radius for selenium of 1.22 Å., which is considerably larger than the value 1.17 A. chosen by Pauling.
| Item Type: | Article | ||||||
|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||
| Additional Information: | © 1955 American Chemical Society. Received January 17, 1955. The support of this work by the Office of Naval Research under Contract N6 onr 24423 is gratefully acknowledged. | ||||||
| Funders: |
| ||||||
| Other Numbering System: |
| ||||||
| Issue or Number: | 11 | ||||||
| DOI: | 10.1021/ja01616a005 | ||||||
| Record Number: | CaltechAUTHORS:20180725-111211759 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180725-111211759 | ||||||
| Official Citation: | An Electron Diffraction Investigation of Dimethyl Selenide Elihu Goldish, Kenneth Hedberg, Richard E. Marsh, and Verner Schomaker Journal of the American Chemical Society 1955 77 (11), 2948-2949 DOI: 10.1021/ja01616a005 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 88269 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 25 Jul 2018 20:10 | ||||||
| Last Modified: | 16 Nov 2021 00:25 |
Repository Staff Only: item control page
