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The Electron Diffraction Investigation of Propargyl Chloride, Bromide, and Iodide

Pauling, Linus and Gordy, Walter and Saylor, John H. (1942) The Electron Diffraction Investigation of Propargyl Chloride, Bromide, and Iodide. Journal of the American Chemical Society, 64 (8). pp. 1753-1756. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20180727-101438424

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Abstract

The surprising discovery that the carbon-carbon single-bond distance in methylacetylene and some related substances is less than the normal value suggested that the study of the propargyl halides would be of interest. We have carried out this study, and have found that the carbon-carbon triple-bond and single-bond distances are the same in these molecules as in methylacetylene, and that the carbon-halogen bond distances are somewhat larger than normal.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja01260a002DOIArticle
Additional Information:© 1942 American Chemical Society. Received May 1, 1942. We are indebted to Dr. V. Schomaker for valuable help in this work.
Funders:
Funding AgencyGrant Number
National Research CouncilUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Gates and Crellin Laboratories of Chemistry878
Record Number:CaltechAUTHORS:20180727-101438424
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20180727-101438424
Official Citation:The Electron Diffraction Investigation of Propargyl Chloride, Bromide, and Iodide Linus Pauling, Walter Gordy, and John H. Saylor Journal of the American Chemical Society 1942 64 (8), 1753-1756 DOI: 10.1021/ja01260a002
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88326
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:30 Jul 2018 18:29
Last Modified:30 Jul 2018 18:29

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