Pauling, Linus and Gordy, Walter and Saylor, John H. (1942) The Electron Diffraction Investigation of Propargyl Chloride, Bromide, and Iodide. Journal of the American Chemical Society, 64 (8). pp. 1753-1756. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20180727-101438424
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Abstract
The surprising discovery that the carbon-carbon single-bond distance in methylacetylene and some related substances is less than the normal value suggested that the study of the propargyl halides would be of interest. We have carried out this study, and have found that the carbon-carbon triple-bond and single-bond distances are the same in these molecules as in methylacetylene, and that the carbon-halogen bond distances are somewhat larger than normal.
| Item Type: | Article | ||||||
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| Additional Information: | © 1942 American Chemical Society. Received May 1, 1942. We are indebted to Dr. V. Schomaker for valuable help in this work. | ||||||
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| Record Number: | CaltechAUTHORS:20180727-101438424 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20180727-101438424 | ||||||
| Official Citation: | The Electron Diffraction Investigation of Propargyl Chloride, Bromide, and Iodide Linus Pauling, Walter Gordy, and John H. Saylor Journal of the American Chemical Society 1942 64 (8), 1753-1756 DOI: 10.1021/ja01260a002 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 88326 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 30 Jul 2018 18:29 | ||||||
| Last Modified: | 30 Jul 2018 18:29 |
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