Stevenson, D. P. and Schomaker, Verner (1939) The Electron Diffraction Investigation of the Molecular Structures of themesoand Racemic 2,3-Dibromobutanes. Journal of the American Chemical Society, 61 (11). pp. 3173-3176. ISSN 0002-7863. doi:10.1021/ja01266a056. https://resolver.caltech.edu/CaltechAUTHORS:20180727-101439200
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Abstract
The recent electron diffraction investigations of the structures of some ethylene halides by Beach and co-workers have provided considerable information regarding the magnitude of the repulsive forces acting between halogen atoms attached to adjacent carbon atoms. In order to extend the work of Beach to the study of the interactions of the methyl group with other methyl groups and with bromine atoms attached to adjacent carbon atoms, meso and racemic 2,3-dibromobutane were selected for electron diffraction investigation. It was hoped that the quite different chemical properties of this pair of molecules might result from an appreciable difference in the relative orientations of the “isopropyl bromide” groups about the 2,3 carbon-carbon single bond, inasmuch as these molecules would be expected to show structural differences in only this respect.
Item Type: | Article | ||||||
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Additional Information: | © 1939 American Chemical Society. Received September 6, 1939. | ||||||
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Issue or Number: | 11 | ||||||
DOI: | 10.1021/ja01266a056 | ||||||
Record Number: | CaltechAUTHORS:20180727-101439200 | ||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180727-101439200 | ||||||
Official Citation: | The Electron Diffraction Investigation of the Molecular Structures of the meso and Racemic 2,3-Dibromobutanes D. P. Stevenson and Verner Schomaker Journal of the American Chemical Society 1939 61 (11), 3173-3176 DOI: 10.1021/ja01266a056 | ||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
ID Code: | 88334 | ||||||
Collection: | CaltechAUTHORS | ||||||
Deposited By: | George Porter | ||||||
Deposited On: | 30 Jul 2018 21:26 | ||||||
Last Modified: | 16 Nov 2021 00:26 |
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