Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

Hanratty, M. A. and Carter, E. A. and Beauchamp, J. L. and Goddard, W. A., III and Illies, A. J. and Bowers, M. T. (1986) Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy. Chemical Physics Letters, 123 (4). pp. 239-242. ISSN 0009-2614. doi:10.1016/0009-2614(86)80064-1. https://resolver.caltech.edu/CaltechAUTHORS:20180731-152042927

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Abstract

The electronic states of the unsaturated organometallic carbene CrCH_2^+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, ^6B_1, and ^6A_1 at 0.78 and 0.82 eV respectively, above the ^4B_1 ground state of CrCH_2^+.

Item Type:

Article

Related URLs:

URL	URL Type	Description
https://doi.org/10.1016/0009-2614(86)80064-1	DOI	Article
https://www.sciencedirect.com/science/article/pii/0009261486800641	Publisher	Article

ORCID:

Author	ORCID
Carter, E. A.	0000-0001-7330-7554
Beauchamp, J. L.	0000-0001-8839-4822
Goddard, W. A., III	0000-0003-0097-5716

Additional Information:

© 1986 Published by Elsevier B.V. Received 4 November 1985. Arthur Amos Noyes Laboratory of Chemical Physics Contribution No. 7320. This work was supported by the National Science Foundation under Grants No. CHE-8318041 (WAG), CHE-8020464 (MTB) and CHE-8407857 (JLB). Support from the Shell Development Company (WAG) and the Atlantic Richfield Foundation (MAH graduate fellowship) is gratefully acknowledged. EAC acknowledges a National Science Foundation predoctoral fellowship (1982-1985).

Funders:

Funding Agency	Grant Number
NSF	CHE-8318041
NSF	CHE-8020464
NSF	CHE-8407857
Shell Development Company	UNSPECIFIED
Atlantic Richfield Foundation	UNSPECIFIED
NSF Predoctoral Fellowship	UNSPECIFIED

Other Numbering System:

Other Numbering System Name	Other Numbering System ID
WAG	0210
Arthur Amos Noyes Laboratory of Chemical Physics	7320

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DOI:

10.1016/0009-2614(86)80064-1

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CaltechAUTHORS:20180731-152042927

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https://resolver.caltech.edu/CaltechAUTHORS:20180731-152042927

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ID Code:

88410

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CaltechAUTHORS

Deposited By:

Donna Wrublewski

Deposited On:

31 Jul 2018 22:33

Last Modified:

16 Nov 2021 00:26

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