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Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

Hanratty, M. A. and Carter, E. A. and Beauchamp, J. L. and Goddard, W. A., III and Illies, A. J. and Bowers, M. T. (1986) Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy. Chemical Physics Letters, 123 (4). pp. 239-242. ISSN 0009-2614. http://resolver.caltech.edu/CaltechAUTHORS:20180731-152042927

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Abstract

The electronic states of the unsaturated organometallic carbene CrCH_2^+ are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 ±0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, ^6B_1, and ^6A_1 at 0.78 and 0.82 eV respectively, above the ^4B_1 ground state of CrCH_2^+.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/0009-2614(86)80064-1DOIArticle
https://www.sciencedirect.com/science/article/pii/0009261486800641PublisherArticle
ORCID:
AuthorORCID
Beauchamp, J. L.0000-0001-8839-4822
Goddard, W. A., III0000-0003-0097-5716
Additional Information:© 1986 Published by Elsevier B.V. Received 4 November 1985. Arthur Amos Noyes Laboratory of Chemical Physics Contribution No. 7320. This work was supported by the National Science Foundation under Grants No. CHE-8318041 (WAG), CHE-8020464 (MTB) and CHE-8407857 (JLB). Support from the Shell Development Company (WAG) and the Atlantic Richfield Foundation (MAH graduate fellowship) is gratefully acknowledged. EAC acknowledges a National Science Foundation predoctoral fellowship (1982-1985).
Funders:
Funding AgencyGrant Number
NSFCHE-8318041
NSFCHE-8020464
NSFCHE-8407857
Shell Development CompanyUNSPECIFIED
Atlantic Richfield FoundationUNSPECIFIED
NSF Predoctoral FellowshipUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
WAG0210
Arthur Amos Noyes Laboratory of Chemical Physics7320
Record Number:CaltechAUTHORS:20180731-152042927
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20180731-152042927
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88410
Collection:CaltechAUTHORS
Deposited By: Donna Wrublewski
Deposited On:31 Jul 2018 22:33
Last Modified:31 Jul 2018 22:33

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