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Location and molecular motion of hexamethylbenzene in zeolite NaY

Hong, Suk Bong and Cho, Herman M. and Davis, Mark E. (1993) Location and molecular motion of hexamethylbenzene in zeolite NaY. Journal of Physical Chemistry, 97 (8). pp. 1629-1633. ISSN 0022-3654. doi:10.1021/j100110a026. https://resolver.caltech.edu/CaltechAUTHORS:20180801-081310389

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Abstract

Hexamethylbenzene (HMB) adsorbed into the supercages of zeolite Na-Y is characterized by thermogravimetric analyses, proton NMR, ^(13)C NMR, proton multiple-quantum NMR, and UV, reflectance and emission spectroscopies. Room temperature, proton multiple-quantum NMR results reveal that the intracrystalline distribution of HMB is primarily pairwise at bulk concentrations of 0.5, 1.0, and 2.0 molecules per supercage. Results from emission spectroscopy suggest that the HMB pairs are uniformly dispersed among the intracrystalline supercages of Na-Y.


Item Type:Article
Related URLs:
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https://doi.org/10.1021/j100110a026DOIArticle
ORCID:
AuthorORCID
Davis, Mark E.0000-0001-8294-1477
Additional Information:© 1993 American Chemical Society. Received: May 14, 1992; In Final Form: October 22, 1992. Support of this work was provided by the NSF Alan T. Waterman Award to M.E.D. We thank Professor G. R. Rossman of the Geology Department at Caltech for assistance in obtaining UV reflectance spectra.
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NSFUNSPECIFIED
Issue or Number:8
DOI:10.1021/j100110a026
Record Number:CaltechAUTHORS:20180801-081310389
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180801-081310389
Official Citation:Location and molecular motion of hexamethylbenzene in zeolite NaY. Suk Bong Hong, Herman M. Cho, and Mark E. Davis. The Journal of Physical Chemistry 1993 97 (8), 1629-1633 DOI: 10.1021/j100110a026
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88421
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:01 Aug 2018 16:21
Last Modified:16 Nov 2021 00:26

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