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Photoinduced electron transfer in ruthenium-modified cytochrome c

Gray, Harry B. and Winkler, Jay R. (1992) Photoinduced electron transfer in ruthenium-modified cytochrome c. Pure and Applied Chemistry, 64 (9). pp. 1257-1262. ISSN 0033-4545. doi:10.1351/pac199264091257. https://resolver.caltech.edu/CaltechAUTHORS:20180808-101753428

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Abstract

Distant heme-Ru electronic couplings have been extracted from intramolecular electron-transfer rates in Ru(histidine-X) (X=33,39,62) derivatives of cytochrome c. The rates (and the couplings) correlate with the lengths of σ-tunneling pathways comprised of covalent bonds, hydrogen bonds, and through-space jumps from the histidines to the heme group.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1351/pac199264091257DOIArticle
ORCID:
AuthorORCID
Gray, Harry B.0000-0002-7937-7876
Winkler, Jay R.0000-0002-4453-9716
Additional Information:© 1992 IUPAC.
Issue or Number:9
DOI:10.1351/pac199264091257
Record Number:CaltechAUTHORS:20180808-101753428
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20180808-101753428
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:88655
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:08 Aug 2018 17:24
Last Modified:16 Nov 2021 00:28

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