Shi, Chunnian and Steiger, Beat and Anson, Fred C. (1995) Coordination chemistry in electrocatalysis. Pure and Applied Chemistry, 67 (2). pp. 319-322. ISSN 0033-4545. doi:10.1351/pac199567020319. https://resolver.caltech.edu/CaltechAUTHORS:20180809-152106160
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Abstract
Superior electrocatalysts for the reduction of O_2 by four-electrons in one step have been prepared by coordinating ammine complexes of Ru(II) to the pyridine ligand sites in cobalt tetrakis(4-pyridyl) porphyrin. At least three coordinated Ru(II) centers appear to be required to obtain the four-electron reduction. When fac-Ru(NH_3)_3(OH_2)_3^(2+) was used to ruthenate the porphyrin, a network structure was obtained in which both terminal and bridging ruthenium centers were present.
| Item Type: | Article | ||||||||
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| Additional Information: | © 1995 IUPAC. This work was supported by the National Science Foundation and the Office of Naval Research/DARPA. | ||||||||
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| Issue or Number: | 2 | ||||||||
| DOI: | 10.1351/pac199567020319 | ||||||||
| Record Number: | CaltechAUTHORS:20180809-152106160 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20180809-152106160 | ||||||||
| Official Citation: | Pure and Applied Chemistry, Volume 67, Issue 2, Pages 319–322, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: https://doi.org/10.1351/pac199567020319 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 88717 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | George Porter | ||||||||
| Deposited On: | 09 Aug 2018 22:34 | ||||||||
| Last Modified: | 16 Nov 2021 00:29 |
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