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Ternary nucleation of H_2SO_4, NH_3 and H_2O

Kulmala, M. and Korhonen, P. and Laaksonen, A. and Viisanen, Y. and McGraw, R. and Seinfeld, J. H. (2000) Ternary nucleation of H_2SO_4, NH_3 and H_2O. In: Nucleation and atmospheric aerosols 2000 : 15th International Conference, Rolla, Missouri, 6-11 August 2000. AIP Conference Proceedings. No.534. American Institute of Physics , Melville, NY, pp. 111-114. ISBN 1-56396-958-0. http://resolver.caltech.edu/CaltechAUTHORS:KULaipcp00a

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Abstract

A classical theory of the ternary homogeneous nucleation of sulfuric acid—ammonia—water is presented. For NH3 mixing ratios exceeding 1 ppt, the presence of ammonia enhances the binary (sulfuric acid—water) nucleation rate by several orders of magnitude. However, the limiting component for ternary nucleation—as for binary nucleation—is sulfuric acid. The sulfuric acid concentration needed for significant ternary nucleation is several orders of magnitude below that required in binary case.


Item Type:Book Section
ORCID:
AuthorORCID
Seinfeld, J. H.0000-0003-1344-4068
Additional Information:© 2000 American Institute of Physics.
Subject Keywords:nucleation; aerosols; particle size measurement; modelling; thermodynamic properties
Record Number:CaltechAUTHORS:KULaipcp00a
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:KULaipcp00a
Alternative URL:http://dx.doi.org/10.1063/1.1361826
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:8930
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:02 Oct 2007
Last Modified:20 Sep 2017 21:17

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