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Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy:  Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex

Agapie, Theodor and Diaconescu, Paula L. and Cummins, Christopher C. (2002) Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy:  Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex. Journal of the American Chemical Society, 124 (11). pp. 2412-2413. ISSN 0002-7863. doi:10.1021/ja017278r. https://resolver.caltech.edu/CaltechAUTHORS:20181106-085445876

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Abstract

Methine (CH) transfer to an open coordination site was achieved in one pot by titanium(III) abstraction of Cl from 7-chloronorbornadiene, radical capture by Mo, and benzene extrusion. This efficient Mo methylidyne synthesis permitted elaboration to an anionic phosphaisocyanide derivative upon deprotonation, functionalization with dichlorophenylphosphine, and ultimate reduction.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/ja017278rDOIArticle
http://pubs.acs.org/doi/pdf/10.1021/ja017278rPublisherArticle
https://pubs.acs.org/doi/suppl/10.1021/ja017278rPublisherSupporting Information
ORCID:
AuthorORCID
Agapie, Theodor0000-0002-9692-7614
Diaconescu, Paula L.0000-0003-2732-4155
Additional Information:© 2002 American Chemical Society. Received October 10, 2001. For support of this work, the authors are grateful to the National Science Foundation (CHE-9988806), the Packard Foundation (Fellowship to C.C.C., 1995-2000), and the National Science Board (Alan T. Waterman award to C.C.C., 1998). T.A. thanks MIT’s UROP (Undergraduate Research Opportunities Program) for funding. The authors thank a referee for drawing attention to ref 12.
Funders:
Funding AgencyGrant Number
NSFCHE-9988806
David and Lucile Packard FoundationUNSPECIFIED
Massachusetts Institute of Technology (MIT)UNSPECIFIED
Issue or Number:11
DOI:10.1021/ja017278r
Record Number:CaltechAUTHORS:20181106-085445876
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20181106-085445876
Official Citation:Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy:  Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex Theodor Agapie,Paula L. Diaconescu, and, and Christopher C. Cummins* Journal of the American Chemical Society 2002 124 (11), 2412-2413 DOI: 10.1021/ja017278r
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:90662
Collection:CaltechAUTHORS
Deposited By: Donna Wrublewski
Deposited On:06 Nov 2018 17:50
Last Modified:16 Nov 2021 03:34

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