Agapie, Theodor and Diaconescu, Paula L. and Cummins, Christopher C. (2002) Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy: Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex. Journal of the American Chemical Society, 124 (11). pp. 2412-2413. ISSN 0002-7863. doi:10.1021/ja017278r. https://resolver.caltech.edu/CaltechAUTHORS:20181106-085445876
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Abstract
Methine (CH) transfer to an open coordination site was achieved in one pot by titanium(III) abstraction of Cl from 7-chloronorbornadiene, radical capture by Mo, and benzene extrusion. This efficient Mo methylidyne synthesis permitted elaboration to an anionic phosphaisocyanide derivative upon deprotonation, functionalization with dichlorophenylphosphine, and ultimate reduction.
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Additional Information: | © 2002 American Chemical Society. Received October 10, 2001. For support of this work, the authors are grateful to the National Science Foundation (CHE-9988806), the Packard Foundation (Fellowship to C.C.C., 1995-2000), and the National Science Board (Alan T. Waterman award to C.C.C., 1998). T.A. thanks MIT’s UROP (Undergraduate Research Opportunities Program) for funding. The authors thank a referee for drawing attention to ref 12. | ||||||||||||
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Issue or Number: | 11 | ||||||||||||
DOI: | 10.1021/ja017278r | ||||||||||||
Record Number: | CaltechAUTHORS:20181106-085445876 | ||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20181106-085445876 | ||||||||||||
Official Citation: | Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy: Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex Theodor Agapie,Paula L. Diaconescu, and, and Christopher C. Cummins* Journal of the American Chemical Society 2002 124 (11), 2412-2413 DOI: 10.1021/ja017278r | ||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
ID Code: | 90662 | ||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||
Deposited By: | Donna Wrublewski | ||||||||||||
Deposited On: | 06 Nov 2018 17:50 | ||||||||||||
Last Modified: | 16 Nov 2021 03:34 |
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