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Simultaneous electrochemical production of hydrogen peroxide and degradation of organic pollutants

Lim, Jonghun and Hoffmann, Michael R. (2018) Simultaneous electrochemical production of hydrogen peroxide and degradation of organic pollutants. In: 256th American Chemical Society National Meeting & Exposition, 19-23 August 2018, Boston, MA. https://resolver.caltech.edu/CaltechAUTHORS:20181108-162111125

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Abstract

We investigated the effect of org. pollutants on the prodn. of hydrogen peroxide (H_2O_2) in the presence of Na_2SO_4 as an electrolyte under oxygen condition. TiO_2/IrO_2, graphite rod, and Ag/AgCl were used as an anode, a cathode, and a ref. electrode, resp. The electrochem. prodn. of H_2O_2 was significantly enhanced in the presence of org. pollutants. This result is ascribed to that the presence of org. pollutants reduces the anodic decompn. of H_2O_2. Org. pollutants prevent the surface complexation between hydroxyl group on the anode surface and H_2O_2. Furthermore, they can be acted as a scavenger of surface-bound hydroxyl radicals that decomp. H_2O_2. We also confirmed that the prodn. of H_2O_2 coupled with the degrdn. of org. pollutants at acidic pH than that at alk. condition. H_2O_2 is mainly produced via the proton coupled electron transfer (PCET) to oxygen. Org. pollutants are highly degraded at acidic condition, because they are electrostatically attracted with the anode surface and surface-bound OH radicals are more generated at a lower pH. This result indicates that the acidic pH provides a better condition for the degrdn. of org. pollutants and prodn. of H_2O_2.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
https://global.acs.org/events/256th-acs-national-meeting-expositionOrganizationConference Website
ORCID:
AuthorORCID
Lim, Jonghun0000-0002-2943-1846
Hoffmann, Michael R.0000-0001-6495-1946
Additional Information:© 2018 American Chemical Society.
Record Number:CaltechAUTHORS:20181108-162111125
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20181108-162111125
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:90778
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:13 Nov 2018 18:06
Last Modified:09 Mar 2020 13:19

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